Unravelling the secrets of Cu-based catalysts for C-H activation

Informazioni relative al progetto

CUBE

ID dell’accordo di sovvenzione: 856446

DOI

10.3030/856446

Data della firma CE 15 Novembre 2019

Data di avvio 1 Maggio 2020

Data di completamento 31 Ottobre 2026

Finanziato da

• EXCELLENT SCIENCE - European Research Council (ERC)

Costo totale

€ 9 885 989,13

Contributo UE

€ 9 885 988,00

Coordinato da

UNIVERSITETET I OSLO
Norway

CORDIS fornisce collegamenti ai risultati finali pubblici e alle pubblicazioni dei progetti ORIZZONTE.

I link ai risultati e alle pubblicazioni dei progetti del 7° PQ, così come i link ad alcuni tipi di risultati specifici come dataset e software, sono recuperati dinamicamente da .OpenAIRE .

Pubblicazioni

Peer reviewed articles (32)

X-ray absorption and emission spectroscopy of N₂S₂ Cu(<scp>ii</scp>)/(<scp>iii</scp>) complexes

Autori: Blaise L. Geoghegan; Jessica K. Bilyj; Paul V. Bernhardt; Serena DeBeer; George E. Cutsail
Pubblicato in: Dalton Transactions, Numero 53, 2024, Pagina/e 7828–7838, ISSN 1477-9226
Editore: Royal Society of Chemistry
DOI: 10.1039/d4dt00085d

Structural Elucidation, Aggregation, and Dynamic Behaviour of N,N,N,N-Copper(I) Schiff Base Complexes in Solid and in Solution: A Combined NMR, X-ray Spectroscopic and Crystallographic Investigation

Autori: Isabelle Gerz, Dr. Sergio Augusto Venturinelli Jannuzzi, Dr. Knut T. Hylland, Dr. Chiara Negri, Dr. David S. Wragg, Dr. Sigurd Øien-Ødegaard, Prof. Mats Tilset, Prof. Unni Olsbye, Prof. Serena DeBeer, Prof. Mohamed Amedjkouh
Pubblicato in: European Journal of Inorganic Chemistry, Numero 46, 2021, Pagina/e 4762-4775, ISSN 1099-0682
Editore: Wiley-VCH GmbH
DOI: 10.1002/ejic.202100722

Expanding the catalytic landscape of metalloenzymes with lytic polysaccharide monooxygenases

Autori: Munzone A, Eijsink VGH, Berrin JG, Bissaro B
Pubblicato in: Nature Reviews Chemistry, Numero Volume 8, February 2024, 2024, Pagina/e 106-119, ISSN 2397-3358
Editore: Nature Springer
DOI: 10.1038/s41570-023-00565-z

Modulation of [CuOH/O]⁺ Properties in [2,2′-Bipyridine]₂ Homoleptic Complexes through Substitution at the 6,6’ Position by Methyl Groups

Autori: Alessandro Damin; Matteo Bonomo; Barbara Centrella; Matteo Signorile; Claudia Barolo; Silvia Bordiga
Pubblicato in: ACS Omega, Numero Volume 9, Numero 14, 2024, Pagina/e 16610−16620, ISSN 2470-1343
Editore: American Chemical Society
DOI: 10.1021/acsomega.4c00598

Exploring Ce(IV)-MOFs redox behavior for catalysis by spectroscopies

Autori: Valeria Finelli, Sergio Rojas-Buzo, Matteo Signorile, Francesca Bonino, Silvia Bordiga
Pubblicato in: Nano Materials Science, 2024, ISSN 2589-9651
Editore: Elsevier B.V.
DOI: 10.1016/j.nanoms.2024.11.001

Synthesis of a mixed-linker Ce-UiO-67 metal–organic framework

Autori: V. Finelli, G. Mastronardi, N. G. Porcaro, M. Signorile, F. Bonino, P. Á. Szilágyi, S. Bordiga
Pubblicato in: RSC Applied Interfaces, 2024, ISSN 2755-3701
Editore: Royal Society of Chemistry
DOI: 10.1039/d4lf00278d

Ancestral sequence reconstruction as a tool to study the evolution of wood decaying fungi

Autori: Iván Ayuso-Fernández; Gonzalo Molpeceres; Susana Camarero; Francisco Javier Ruiz-Dueñas; Angel T. Martínez
Pubblicato in: Frontiers in Fungal Biology, Numero Volume 3, article 1003489, 2022, ISSN 2673-6128
Editore: Frontiers Media S.A.
DOI: 10.3389/ffunb.2022.1003489

Electrochemical Monitoring of Heterogeneous Peroxygenase Reactions Unravels LPMO Kinetics

Autori: Lorenz Schwaiger; Florian Csarman; Hucheng Chang; Ole Golten; Vincent G. H. Eijsink; Roland Ludwig
Pubblicato in: ACS Catalysis, Numero Volume14, January 2024, 2024, Pagina/e 1205−1219, ISSN 2155-5435
Editore: American Chemical Society
DOI: 10.1021/acscatal.3c05194

Mutational dissection of a hole hopping route in a lytic polysaccharide monooxygenase (LPMO)

Autori: Ivan Ayuso-Fernández, Tom Z. Emrich-Mills, Julia Haak, Ole Golten, Kelsi R. Hall, Lorentz Schwaiger, Trond S. Moe, Anton A. Stepnov, Roland Ludwig, Georg E. Cutsail III, Morten Sørlie, Åsmund Kjendseth Røhr, Vincent G. H. Eijsink
Pubblicato in: Nature Communications, Numero Volume 15, Article 3975, May 2024, 2024, ISSN 2041-1723
Editore: Nature Publishing Group
DOI: 10.1038/s41467-024-48245-w

Copper(II)-Oxyl Formation in a Biomimetic Complex Activated by Hydrogen Peroxide: The Key Role of Trans-Bis(Hydroxo) Species

Autori: Ning Cao, Abril C. Castro, David Balcells, Unni Olsbye, Ainara Nova
Pubblicato in: Inorganic Chemistry, Numero 63, 2024, Pagina/e 23082-23094, ISSN 0020-1669
Editore: American Chemical Society
DOI: 10.1021/acs.inorgchem.4c01948

Combining Valence-to-Core X-ray Emission and Cu K-edge X-ray Absorption Spectroscopies to Experimentally Assess Oxidation State in Organometallic Cu(I)/(II)/(III) Complexes

Autori: Blaise L. Geoghegan; Yang Liu; Sergey Peredkov; Sebastian Dechert; Franc Meyer; Serena DeBeer; George E. Cutsail
Pubblicato in: Journal of the American Chemical Society, Numero Volume 144, issue 6, January 2022, 2022, Pagina/e 2520–2534, ISSN 0002-7863
Editore: American Chemical Society
DOI: 10.1021/jacs.1c09505

Copper Pairing in the Mordenite Framework as a Function of the CuI/CuII Speciation

Autori: Gabriele Deplano, Dr. Andrea Martini, Dr. Matteo Signorile, Dr. Elisa Borfecchia, Dr. Valentina Crocellà, Prof. Stian Svelle, Prof. Silvia Bordiga
Pubblicato in: Angewandte Chemie, Numero 49, 2021, Pagina/e 25891-25896, ISSN 1521-3757
Editore: Wiley-VCH GmbH
DOI: 10.1002/anie.202109705

Partial oxidation of cyclohexene over histidine-modified Cu-UiO-66 under aerobic conditions

Autori: Erlend Aunan, Valeria Finelli, Sebastian Prodinger, Ning Cao, Beatrice Garetto, Gabriele Deplano, Peter Ng’ang’a Njoroge, Matteo Signorile, Elisa Borfecchia, Karl Petter Lillerud, Ainara Nova, Silvia Bordiga, Unni Olsbye
Pubblicato in: Journal of Catalysis, Numero 438, 2024, Pagina/e 115722, ISSN 0021-9517
Editore: Academic Press
DOI: 10.1016/j.jcat.2024.115722

Impact of the copper second coordination sphere on catalytic performance and substrate specificity of a bacterial LPMO

Autori: Kelsi R. Hall, Maja Mollatt, Zarah Forsberg, Ole Golten, Lorenz Schwaiger, Roland Ludwig, Iván Ayuso-Fernández, Vincent G.H. Eijsink, Morten Sørlie
Pubblicato in: ACS Omega, Numero Volume 9, May 2024, 2024, Pagina/e 23040-23052, ISSN 2470-1343
Editore: American Chemical Society
DOI: 10.1021/acsomega.4c02666

Titration of Cu(I) Sites in Cu-ZSM-5 by Volumetric CO Adsorption

Autori: Gabriele Deplano, Matteo Signorile, Valentina Crocellà, Natale Gabriele Porcaro, Cesare Atzori, Bjørn Gading Solemsli, Stian Svelle, and Silvia Bordiga*
Pubblicato in: ACS Applied Materials & Interfaces, Numero Volume 14, Numero 18, April 2022, 2022, Pagina/e 21059–21068, ISSN 1944-8244
Editore: American Chemical Society
DOI: 10.1021/acsami.2c03370

Cation-induced speciation of port-size during mordenite zeolite synthesis

Autori: Sebastian Prodinger; Izar Capel Berdiell; Tomas Cordero-Lanzac; Odd Reidar Bygdnes; Bjørn Gading Solemsli; Karoline Kvande; Bjørnar Arstad; Pablo Beato; Unni Olsbye; Stian Svelle
Pubblicato in: Journal of Materials Chemistry A, Numero Volume 11, 2023, Pagina/e 21884–21894, ISSN 2050-7488
Editore: Royal Society of Chemistry
DOI: 10.1039/d3ta03444e

Reducibility of Cu-zeolites and stability of Cu+ monocarbonyl adducts: Qualitative and quantitative relationships from MCR-XAS and DFT

Autori: Gabriele Deplano; Matteo Signorile; Cesare Atzori; Davide Salusso; Elisa Borfecchia; Valentina Crocellà; Silvia Bordiga
Pubblicato in: Catalysis Today, Numero Volume 427, 114403,, 2023, ISSN 0920-5861
Editore: Elsevier BV
DOI: 10.1016/j.cattod.2023.114403

A Conserved Second Sphere Residue Tunes Copper Site Reactivity in Lytic Polysaccharide Monooxygenases

Autori: Kelsi R. Hall; Chris Joseph; Iván Ayuso-Fernández; Ashish Tamhankar; Lukas Rieder; Rannei Skaali; Ole Golten; Frank Neese; Åsmund K. Røhr; Sergio A. V. Jannuzzi; Serena DeBeer; Vincent G. H. Eijsink; Morten Sørlie
Pubblicato in: Journal of the American Chemical Society, Numero Volume 145, pages 18888-18903, August 2023, 2023, ISSN 0002-7863
Editore: American Chemical Society
DOI: 10.1021/jacs.3c05342

Investigating the role of Cu-oxo species in Cu-nitrate formation over Cu-CHA catalysts.

Autori: Chiara Negri; Andrea Martini; Gabriele Deplano; Kirill A. Lomachenko; Ton V. W. Janssens; Elisa Borfecchia; Gloria Berlier; Silvia Bordiga
Pubblicato in: Physical Chemistry Chemical Physics, Numero 23, 2021, Pagina/e 18322-18337, ISSN 1463-9084
Editore: The Royal Society of Chemistry
DOI: 10.1039/d1cp01754c

Integrated Experimental and Theoretical Investigation of Copper Active Site Properties of a Lytic Polysaccharide Monooxygenase from Serratia marcescens

Autori: Alessia Munzone, Manon Pujol, Ashish Tamhankar, Chris Joseph, Ievgen Mazurenko, Marius Réglier, Sergio A. V. Jannuzzi, Antoine Royant, Giuseppe Sicoli, Serena DeBeer, Maylis Orio, A. Jalila Simaan, and Christophe Decroos
Pubblicato in: Inorganic Chemistry, Numero Volume 63, Numero 24, 2024, Pagina/e 11063-11078, ISSN 0020-1669
Editore: American Chemical Society
DOI: 10.1021/acs.inorgchem.4c00602

Lytic polysaccharide monooxygenases: enzymes for controlled and site-specific Fenton-like chemistry

Autori: B. Bissaro & V.G.H. Eijsink
Pubblicato in: Essays in Biochemistry, Numero Mar 18;Volume 67, issue 3, March 2023, 2023, Pagina/e 575-584, ISSN 0071-1365
Editore: Portland Press, Ltd.
DOI: 10.1042/ebc20220250

Reductants fuel lytic polysaccharide monooxygenase activity in a pH-dependent manner

Autori: Ole Golten, Iván Ayuso-Fernández, Kelsi R. Hall, Anton A. Stepnov, Morten Sørlie, Åsmund Kjendseth Røhr, Vincent G. H. Eijsink
Pubblicato in: FEBS Letters, Numero Volume 597, Numero 10, 2023, Pagina/e 1363-1374, ISSN 0014-5793
Editore: Elsevier BV
DOI: 10.1002/1873-3468.14629

Understanding C–H activation in light alkanes over Cu-MOR zeolites by coupling advanced spectroscopy and temperature-programmed reduction experiments

Autori: Karoline Kvande; Beatrice Garetto; Gabriele Deplano; Matteo Signorile; Bjørn Gading Solemsli; Sebastian Prodinger; Unni Olsbye; Pablo Beato; Silvia Bordiga; Stian Svelle; Elisa Borfecchia
Pubblicato in: Chemical Science, Numero August 2023, volume 14, 2023, Pagina/e 9704–9723, ISSN 2041-6520
Editore: Royal Society of Chemistry
DOI: 10.1039/d3sc01677c

A multi-technique approach to unveil the redox behaviour and potentiality of homoleptic CuI complexes based on substituted bipyridine ligands in oxygenation reactions

Autori: Barbara Centrella; Gabriele Deplano; Alessandro Damin; Matteo Signorile; Mariagrazia Tortora; Claudia Barolo; Matteo Bonomo; Silvia Bordiga
Pubblicato in: Dalton Transactions, Numero Numero 51, July 2022, 2022, Pagina/e 14439-14451, ISSN 1477-9234
Editore: The Royal Society of Chemistry
DOI: 10.1039/d2dt01234k

"The ""life-span"" of lytic polysaccharide monooxygenases (LPMOs) correlates to the number of turnovers in the reductant peroxidase reaction"

Autori: Kuusk S, Eijsink VGH, Väljamäe P.
Pubblicato in: Journal of Biological Chemistry, Numero Volume 299, Numero 9, Article 105094, Sep 2023, 2023, ISSN 1083-351X
Editore: Elsevier BV
DOI: 10.1016/j.jbc.2023.105094

Reactivity of methoxy species towards methylation and oligomerization in Cu-zeolite systems

Autori: Bjørn Gading Solemsli, Izar Capel Berdiell, Sebastian Prodinger, Karoline Kvande, Gabriele Deplano, Unni Olsbye, Pablo Beato, Silvia Bordiga, Stian Svelle
Pubblicato in: Catalysis Today, Numero Volume 436, Article 114729, 2024, ISSN 0920-5861
Editore: Elsevier BV
DOI: 10.1016/j.cattod.2024.114729

Towards a unified understanding of the copper sites in particulate methane monooxygenase: an X-ray absorption spectroscopic investigation

Autori: George E. Cutsail; Matthew O. Ross; Amy C. Rosenzweig; Serena DeBeer
Pubblicato in: Chemical Science, Numero 12, 2021, Pagina/e 6194-6209, ISSN 2041-6539
Editore: The Royal Society of Chemistry
DOI: 10.1039/d1sc00676b

Assessing the Influence of Zeolite Composition on Oxygen-Bridged Diamino Dicopper(II) Complexes in Cu-CHA DeNO_<i>x</i> Catalysts by Machine Learning-Assisted X-ray Absorption Spectroscopy

Autori: Andrea Martini; Chiara Negri; Luca Bugarin; Gabriele Deplano; Reza K. Abasabadi; Kirill A. Lomachenko; Ton V. W. Janssens; Silvia Bordiga; Gloria Berlier; Elisa Borfecchia
Pubblicato in: The Journal of Physical Chemistry Letters, Numero Volume 13, Numero 26, July 2022, 2022, Pagina/e 6164-6170, ISSN 1948-7185
Editore: American Chemical Society
DOI: 10.1021/acs.jpclett.2c01107

Enabling a bioinspired <i>N</i>,<i>N</i>,<i>N</i>-copper coordination motif through spatial control in UiO-67: synthesis and reactivity

Autori: Isabelle Gerz; Erlend S. Aunan; Valeria Finelli; Mouhammad Abu Rasheed; Gabriele Deplano; Rafael Cortez S. P.; Inga L. Schmidtke; David S. Wragg; Matteo Signorile; Knut T. Hylland; Elisa Borfecchia; Karl Petter Lillerud; Silvia Bordiga; Unni Olsbye; Mohamed Amedjkouh
Pubblicato in: Dalton Transactions, Numero Volume 53, 2024, Pagina/e 8141-8153, ISSN 1477-9226
Editore: Royal Society of Chemistry
DOI: 10.1039/d3dt03096b

Visible light-exposed lignin facilitates cellulose solubilization by lytic polysaccharide monooxygenases

Autori: Eirik G. Kommedal; Camilla F. Angeltveit; Leesa J. Klau; Iván Ayuso-Fernández; Bjørnar Arstad; Simen G. Antonsen; Yngve Stenstrøm; Dag Ekeberg; Francisco Gírio; Florbela Carvalheiro; Svein J. Horn; Finn Lillelund Aachmann; Vincent G. H. Eijsink
Pubblicato in: Nature Communications, Numero Volume 14, article 1063, 2023, 2023, Pagina/e 1-12, ISSN 2041-1723
Editore: Nature Publishing Group
DOI: 10.1038/s41467-023-36660-4

<i>In situ</i> H₂O₂ Generation by Choline Oxidase and Its Application in Amino Polysaccharide Degradation by Coupling to Lytic Polysaccharide Monooxygenase

Autori: Nam‐Hai Hoang; Ole Golten; Zarah Forsberg; Vincent G. H. Eijsink; Michael Richter
Pubblicato in: ChemBioChem, Numero Volume 16, article e202300363, May 2023, 2023, ISSN 1439-4227
Editore: John Wiley & Sons Ltd.
DOI: 10.1002/cbic.202300363

Influence of ion mobility on the redox and catalytic properties of Cu ions in zeolites

Autori: Signorile, Matteo; Borfecchia, Elisa; Bordiga, Silvia; Berlier, Gloria
Pubblicato in: Chemical Science, Numero Numero 35, August 2022, 2022, Pagina/e 10238-10250, ISSN 2041-6520
Editore: Royal Society of Chemistry
DOI: 10.1039/d2sc03565k

Thesis and dissertations (15)

Coupling of the organic linkers and their simultaneous integration in a missing linker UiO-66 

Autori: Laura Sypalyte
Pubblicato in: 2024
Editore: University of Oslo

Cu-based catalysts for C-H bond activation

Autori: Gabriele Deplano
Pubblicato in: 2023
Editore: University of Turin

Synthesis and Characterization of Metal Organic Frameworks Containing Bio inspired Cu-centers

Autori: Erlend Solbakken Aunan
Pubblicato in: 2024
Editore: University of Oslo

Mimicking the active site of Lytic Polysaccharides Monooxygenases (LPMO) enzymes for catalysisSynthesis and Characterization

Autori: Atiqa Ambrin Ansar
Pubblicato in: 2023
Editore: University of Oslo

Exploring the potential role of lytic polysaccharide monooxygenases from Bacillus licheniformis and Bacillus spizizenii in endospore germination

Autori: Ingeborg Langeby Korsane
Pubblicato in: 2024
Editore: NMBU

Synthesis of bioinspired bidentate N-ligands and their incorporation into UiO-67

Autori: Ingeborg Tangevold
Pubblicato in: 2024
Editore: University of Oslo

Investigating the role of aromatic core residues in protecting against oxidative damage in lytic polysaccharide monooxygenase SmAA10A

Autori: Moe, Trond
Pubblicato in: 2022
Editore: NMBU

The Impact of a Structurally Conserved Second Sphere Residue in Lytic Polysaccharide Monooxygenase Catalysis

Autori: Skaali, Rannei
Pubblicato in: 2022
Editore: NMBU

Bioinspired Copper Complexes for Incorporation into UiO-67

Autori: Isabelle Gerz
Pubblicato in: Numero Volume 2022, Numero 2536, 2022
Editore: University of Oslo

Synthesis and structural characterization of heteroleptic dipyridophenazine–based [Cu(N^N)(P^P)]+ complexes

Autori: Melchizedek Amoakwah
Pubblicato in: 2023
Editore: University of Oslo

Characterization of Zr-MOF containing anchored Cu species for C-H bond activation

Autori: Giuseppe Mastronardi
Pubblicato in: 2023
Editore: University of Turin

The roles of conserved second sphere residues in lytic polysaccharide monooxygenase catalysis

Autori: Mollatt, Maja
Pubblicato in: 2022
Editore: NMBU

Investigating the role of aromatic core residues in protecting against oxidative damage in lytic polysaccharide monooxygenase SmAA10A

Autori: Moe, Trond
Pubblicato in: 2023
Editore: NMBU

Synthesis and characterization of Ce/Zr mixed cluster Metal-Organic Frameworks UiO-67 as catalysts for the partial oxidation of cyclohexene

Autori: Federico Panagini
Pubblicato in: 2024
Editore: University of Turin

A multi-technique approach aimed at developing new Cu-based catalysts for C-H activations: from design, synthesis and characterization to evaluation of their performance

Autori: Barbara Centrella
Pubblicato in: 2024
Editore: University of Turin