Unravelling the secrets of Cu-based catalysts for C-H activation

Informacje na temat projektu

CUBE

Identyfikator umowy o grant: 856446

DOI

10.3030/856446

Data podpisania przez KE 15 Listopada 2019

Data rozpoczęcia 1 Maja 2020

Data zakończenia 31 Października 2026

Finansowanie w ramach

• EXCELLENT SCIENCE - European Research Council (ERC)

Koszt całkowity

€ 9 885 989,13

Wkład UE

€ 9 885 988,00

Koordynowany przez

UNIVERSITETET I OSLO
Norway

CORDIS oferuje możliwość skorzystania z odnośników do publicznie dostępnych publikacji i rezultatów projektów realizowanych w ramach programów ramowych HORYZONT.

Odnośniki do rezultatów i publikacji związanych z poszczególnymi projektami 7PR, a także odnośniki do niektórych konkretnych kategorii wyników, takich jak zbiory danych i oprogramowanie, są dynamicznie pobierane z systemu OpenAIRE .

Publikacje

Peer reviewed articles (32)

X-ray absorption and emission spectroscopy of N₂S₂ Cu(<scp>ii</scp>)/(<scp>iii</scp>) complexes

Autorzy: Blaise L. Geoghegan; Jessica K. Bilyj; Paul V. Bernhardt; Serena DeBeer; George E. Cutsail
Opublikowane w: Dalton Transactions, Numer 53, 2024, Strona(/y) 7828–7838, ISSN 1477-9226
Wydawca: Royal Society of Chemistry
DOI: 10.1039/d4dt00085d

Structural Elucidation, Aggregation, and Dynamic Behaviour of N,N,N,N-Copper(I) Schiff Base Complexes in Solid and in Solution: A Combined NMR, X-ray Spectroscopic and Crystallographic Investigation

Autorzy: Isabelle Gerz, Dr. Sergio Augusto Venturinelli Jannuzzi, Dr. Knut T. Hylland, Dr. Chiara Negri, Dr. David S. Wragg, Dr. Sigurd Øien-Ødegaard, Prof. Mats Tilset, Prof. Unni Olsbye, Prof. Serena DeBeer, Prof. Mohamed Amedjkouh
Opublikowane w: European Journal of Inorganic Chemistry, Numer 46, 2021, Strona(/y) 4762-4775, ISSN 1099-0682
Wydawca: Wiley-VCH GmbH
DOI: 10.1002/ejic.202100722

Expanding the catalytic landscape of metalloenzymes with lytic polysaccharide monooxygenases

Autorzy: Munzone A, Eijsink VGH, Berrin JG, Bissaro B
Opublikowane w: Nature Reviews Chemistry, Numer Volume 8, February 2024, 2024, Strona(/y) 106-119, ISSN 2397-3358
Wydawca: Nature Springer
DOI: 10.1038/s41570-023-00565-z

Modulation of [CuOH/O]⁺ Properties in [2,2′-Bipyridine]₂ Homoleptic Complexes through Substitution at the 6,6’ Position by Methyl Groups

Autorzy: Alessandro Damin; Matteo Bonomo; Barbara Centrella; Matteo Signorile; Claudia Barolo; Silvia Bordiga
Opublikowane w: ACS Omega, Numer Volume 9, Numer 14, 2024, Strona(/y) 16610−16620, ISSN 2470-1343
Wydawca: American Chemical Society
DOI: 10.1021/acsomega.4c00598

Exploring Ce(IV)-MOFs redox behavior for catalysis by spectroscopies

Autorzy: Valeria Finelli, Sergio Rojas-Buzo, Matteo Signorile, Francesca Bonino, Silvia Bordiga
Opublikowane w: Nano Materials Science, 2024, ISSN 2589-9651
Wydawca: Elsevier B.V.
DOI: 10.1016/j.nanoms.2024.11.001

Synthesis of a mixed-linker Ce-UiO-67 metal–organic framework

Autorzy: V. Finelli, G. Mastronardi, N. G. Porcaro, M. Signorile, F. Bonino, P. Á. Szilágyi, S. Bordiga
Opublikowane w: RSC Applied Interfaces, 2024, ISSN 2755-3701
Wydawca: Royal Society of Chemistry
DOI: 10.1039/d4lf00278d

Ancestral sequence reconstruction as a tool to study the evolution of wood decaying fungi

Autorzy: Iván Ayuso-Fernández; Gonzalo Molpeceres; Susana Camarero; Francisco Javier Ruiz-Dueñas; Angel T. Martínez
Opublikowane w: Frontiers in Fungal Biology, Numer Volume 3, article 1003489, 2022, ISSN 2673-6128
Wydawca: Frontiers Media S.A.
DOI: 10.3389/ffunb.2022.1003489

Electrochemical Monitoring of Heterogeneous Peroxygenase Reactions Unravels LPMO Kinetics

Autorzy: Lorenz Schwaiger; Florian Csarman; Hucheng Chang; Ole Golten; Vincent G. H. Eijsink; Roland Ludwig
Opublikowane w: ACS Catalysis, Numer Volume14, January 2024, 2024, Strona(/y) 1205−1219, ISSN 2155-5435
Wydawca: American Chemical Society
DOI: 10.1021/acscatal.3c05194

Mutational dissection of a hole hopping route in a lytic polysaccharide monooxygenase (LPMO)

Autorzy: Ivan Ayuso-Fernández, Tom Z. Emrich-Mills, Julia Haak, Ole Golten, Kelsi R. Hall, Lorentz Schwaiger, Trond S. Moe, Anton A. Stepnov, Roland Ludwig, Georg E. Cutsail III, Morten Sørlie, Åsmund Kjendseth Røhr, Vincent G. H. Eijsink
Opublikowane w: Nature Communications, Numer Volume 15, Article 3975, May 2024, 2024, ISSN 2041-1723
Wydawca: Nature Publishing Group
DOI: 10.1038/s41467-024-48245-w

Copper(II)-Oxyl Formation in a Biomimetic Complex Activated by Hydrogen Peroxide: The Key Role of Trans-Bis(Hydroxo) Species

Autorzy: Ning Cao, Abril C. Castro, David Balcells, Unni Olsbye, Ainara Nova
Opublikowane w: Inorganic Chemistry, Numer 63, 2024, Strona(/y) 23082-23094, ISSN 0020-1669
Wydawca: American Chemical Society
DOI: 10.1021/acs.inorgchem.4c01948

Combining Valence-to-Core X-ray Emission and Cu K-edge X-ray Absorption Spectroscopies to Experimentally Assess Oxidation State in Organometallic Cu(I)/(II)/(III) Complexes

Autorzy: Blaise L. Geoghegan; Yang Liu; Sergey Peredkov; Sebastian Dechert; Franc Meyer; Serena DeBeer; George E. Cutsail
Opublikowane w: Journal of the American Chemical Society, Numer Volume 144, issue 6, January 2022, 2022, Strona(/y) 2520–2534, ISSN 0002-7863
Wydawca: American Chemical Society
DOI: 10.1021/jacs.1c09505

Copper Pairing in the Mordenite Framework as a Function of the CuI/CuII Speciation

Autorzy: Gabriele Deplano, Dr. Andrea Martini, Dr. Matteo Signorile, Dr. Elisa Borfecchia, Dr. Valentina Crocellà, Prof. Stian Svelle, Prof. Silvia Bordiga
Opublikowane w: Angewandte Chemie, Numer 49, 2021, Strona(/y) 25891-25896, ISSN 1521-3757
Wydawca: Wiley-VCH GmbH
DOI: 10.1002/anie.202109705

Partial oxidation of cyclohexene over histidine-modified Cu-UiO-66 under aerobic conditions

Autorzy: Erlend Aunan, Valeria Finelli, Sebastian Prodinger, Ning Cao, Beatrice Garetto, Gabriele Deplano, Peter Ng’ang’a Njoroge, Matteo Signorile, Elisa Borfecchia, Karl Petter Lillerud, Ainara Nova, Silvia Bordiga, Unni Olsbye
Opublikowane w: Journal of Catalysis, Numer 438, 2024, Strona(/y) 115722, ISSN 0021-9517
Wydawca: Academic Press
DOI: 10.1016/j.jcat.2024.115722

Impact of the copper second coordination sphere on catalytic performance and substrate specificity of a bacterial LPMO

Autorzy: Kelsi R. Hall, Maja Mollatt, Zarah Forsberg, Ole Golten, Lorenz Schwaiger, Roland Ludwig, Iván Ayuso-Fernández, Vincent G.H. Eijsink, Morten Sørlie
Opublikowane w: ACS Omega, Numer Volume 9, May 2024, 2024, Strona(/y) 23040-23052, ISSN 2470-1343
Wydawca: American Chemical Society
DOI: 10.1021/acsomega.4c02666

Titration of Cu(I) Sites in Cu-ZSM-5 by Volumetric CO Adsorption

Autorzy: Gabriele Deplano, Matteo Signorile, Valentina Crocellà, Natale Gabriele Porcaro, Cesare Atzori, Bjørn Gading Solemsli, Stian Svelle, and Silvia Bordiga*
Opublikowane w: ACS Applied Materials & Interfaces, Numer Volume 14, Numer 18, April 2022, 2022, Strona(/y) 21059–21068, ISSN 1944-8244
Wydawca: American Chemical Society
DOI: 10.1021/acsami.2c03370

Cation-induced speciation of port-size during mordenite zeolite synthesis

Autorzy: Sebastian Prodinger; Izar Capel Berdiell; Tomas Cordero-Lanzac; Odd Reidar Bygdnes; Bjørn Gading Solemsli; Karoline Kvande; Bjørnar Arstad; Pablo Beato; Unni Olsbye; Stian Svelle
Opublikowane w: Journal of Materials Chemistry A, Numer Volume 11, 2023, Strona(/y) 21884–21894, ISSN 2050-7488
Wydawca: Royal Society of Chemistry
DOI: 10.1039/d3ta03444e

Reducibility of Cu-zeolites and stability of Cu+ monocarbonyl adducts: Qualitative and quantitative relationships from MCR-XAS and DFT

Autorzy: Gabriele Deplano; Matteo Signorile; Cesare Atzori; Davide Salusso; Elisa Borfecchia; Valentina Crocellà; Silvia Bordiga
Opublikowane w: Catalysis Today, Numer Volume 427, 114403,, 2023, ISSN 0920-5861
Wydawca: Elsevier BV
DOI: 10.1016/j.cattod.2023.114403

A Conserved Second Sphere Residue Tunes Copper Site Reactivity in Lytic Polysaccharide Monooxygenases

Autorzy: Kelsi R. Hall; Chris Joseph; Iván Ayuso-Fernández; Ashish Tamhankar; Lukas Rieder; Rannei Skaali; Ole Golten; Frank Neese; Åsmund K. Røhr; Sergio A. V. Jannuzzi; Serena DeBeer; Vincent G. H. Eijsink; Morten Sørlie
Opublikowane w: Journal of the American Chemical Society, Numer Volume 145, pages 18888-18903, August 2023, 2023, ISSN 0002-7863
Wydawca: American Chemical Society
DOI: 10.1021/jacs.3c05342

Investigating the role of Cu-oxo species in Cu-nitrate formation over Cu-CHA catalysts.

Autorzy: Chiara Negri; Andrea Martini; Gabriele Deplano; Kirill A. Lomachenko; Ton V. W. Janssens; Elisa Borfecchia; Gloria Berlier; Silvia Bordiga
Opublikowane w: Physical Chemistry Chemical Physics, Numer 23, 2021, Strona(/y) 18322-18337, ISSN 1463-9084
Wydawca: The Royal Society of Chemistry
DOI: 10.1039/d1cp01754c

Integrated Experimental and Theoretical Investigation of Copper Active Site Properties of a Lytic Polysaccharide Monooxygenase from Serratia marcescens

Autorzy: Alessia Munzone, Manon Pujol, Ashish Tamhankar, Chris Joseph, Ievgen Mazurenko, Marius Réglier, Sergio A. V. Jannuzzi, Antoine Royant, Giuseppe Sicoli, Serena DeBeer, Maylis Orio, A. Jalila Simaan, and Christophe Decroos
Opublikowane w: Inorganic Chemistry, Numer Volume 63, Numer 24, 2024, Strona(/y) 11063-11078, ISSN 0020-1669
Wydawca: American Chemical Society
DOI: 10.1021/acs.inorgchem.4c00602

Lytic polysaccharide monooxygenases: enzymes for controlled and site-specific Fenton-like chemistry

Autorzy: B. Bissaro & V.G.H. Eijsink
Opublikowane w: Essays in Biochemistry, Numer Mar 18;Volume 67, issue 3, March 2023, 2023, Strona(/y) 575-584, ISSN 0071-1365
Wydawca: Portland Press, Ltd.
DOI: 10.1042/ebc20220250

Reductants fuel lytic polysaccharide monooxygenase activity in a pH-dependent manner

Autorzy: Ole Golten, Iván Ayuso-Fernández, Kelsi R. Hall, Anton A. Stepnov, Morten Sørlie, Åsmund Kjendseth Røhr, Vincent G. H. Eijsink
Opublikowane w: FEBS Letters, Numer Volume 597, Numer 10, 2023, Strona(/y) 1363-1374, ISSN 0014-5793
Wydawca: Elsevier BV
DOI: 10.1002/1873-3468.14629

Understanding C–H activation in light alkanes over Cu-MOR zeolites by coupling advanced spectroscopy and temperature-programmed reduction experiments

Autorzy: Karoline Kvande; Beatrice Garetto; Gabriele Deplano; Matteo Signorile; Bjørn Gading Solemsli; Sebastian Prodinger; Unni Olsbye; Pablo Beato; Silvia Bordiga; Stian Svelle; Elisa Borfecchia
Opublikowane w: Chemical Science, Numer August 2023, volume 14, 2023, Strona(/y) 9704–9723, ISSN 2041-6520
Wydawca: Royal Society of Chemistry
DOI: 10.1039/d3sc01677c

A multi-technique approach to unveil the redox behaviour and potentiality of homoleptic CuI complexes based on substituted bipyridine ligands in oxygenation reactions

Autorzy: Barbara Centrella; Gabriele Deplano; Alessandro Damin; Matteo Signorile; Mariagrazia Tortora; Claudia Barolo; Matteo Bonomo; Silvia Bordiga
Opublikowane w: Dalton Transactions, Numer Numer 51, July 2022, 2022, Strona(/y) 14439-14451, ISSN 1477-9234
Wydawca: The Royal Society of Chemistry
DOI: 10.1039/d2dt01234k

"The ""life-span"" of lytic polysaccharide monooxygenases (LPMOs) correlates to the number of turnovers in the reductant peroxidase reaction"

Autorzy: Kuusk S, Eijsink VGH, Väljamäe P.
Opublikowane w: Journal of Biological Chemistry, Numer Volume 299, Numer 9, Article 105094, Sep 2023, 2023, ISSN 1083-351X
Wydawca: Elsevier BV
DOI: 10.1016/j.jbc.2023.105094

Reactivity of methoxy species towards methylation and oligomerization in Cu-zeolite systems

Autorzy: Bjørn Gading Solemsli, Izar Capel Berdiell, Sebastian Prodinger, Karoline Kvande, Gabriele Deplano, Unni Olsbye, Pablo Beato, Silvia Bordiga, Stian Svelle
Opublikowane w: Catalysis Today, Numer Volume 436, Article 114729, 2024, ISSN 0920-5861
Wydawca: Elsevier BV
DOI: 10.1016/j.cattod.2024.114729

Towards a unified understanding of the copper sites in particulate methane monooxygenase: an X-ray absorption spectroscopic investigation

Autorzy: George E. Cutsail; Matthew O. Ross; Amy C. Rosenzweig; Serena DeBeer
Opublikowane w: Chemical Science, Numer 12, 2021, Strona(/y) 6194-6209, ISSN 2041-6539
Wydawca: The Royal Society of Chemistry
DOI: 10.1039/d1sc00676b

Assessing the Influence of Zeolite Composition on Oxygen-Bridged Diamino Dicopper(II) Complexes in Cu-CHA DeNO_<i>x</i> Catalysts by Machine Learning-Assisted X-ray Absorption Spectroscopy

Autorzy: Andrea Martini; Chiara Negri; Luca Bugarin; Gabriele Deplano; Reza K. Abasabadi; Kirill A. Lomachenko; Ton V. W. Janssens; Silvia Bordiga; Gloria Berlier; Elisa Borfecchia
Opublikowane w: The Journal of Physical Chemistry Letters, Numer Volume 13, Numer 26, July 2022, 2022, Strona(/y) 6164-6170, ISSN 1948-7185
Wydawca: American Chemical Society
DOI: 10.1021/acs.jpclett.2c01107

Enabling a bioinspired <i>N</i>,<i>N</i>,<i>N</i>-copper coordination motif through spatial control in UiO-67: synthesis and reactivity

Autorzy: Isabelle Gerz; Erlend S. Aunan; Valeria Finelli; Mouhammad Abu Rasheed; Gabriele Deplano; Rafael Cortez S. P.; Inga L. Schmidtke; David S. Wragg; Matteo Signorile; Knut T. Hylland; Elisa Borfecchia; Karl Petter Lillerud; Silvia Bordiga; Unni Olsbye; Mohamed Amedjkouh
Opublikowane w: Dalton Transactions, Numer Volume 53, 2024, Strona(/y) 8141-8153, ISSN 1477-9226
Wydawca: Royal Society of Chemistry
DOI: 10.1039/d3dt03096b

Visible light-exposed lignin facilitates cellulose solubilization by lytic polysaccharide monooxygenases

Autorzy: Eirik G. Kommedal; Camilla F. Angeltveit; Leesa J. Klau; Iván Ayuso-Fernández; Bjørnar Arstad; Simen G. Antonsen; Yngve Stenstrøm; Dag Ekeberg; Francisco Gírio; Florbela Carvalheiro; Svein J. Horn; Finn Lillelund Aachmann; Vincent G. H. Eijsink
Opublikowane w: Nature Communications, Numer Volume 14, article 1063, 2023, 2023, Strona(/y) 1-12, ISSN 2041-1723
Wydawca: Nature Publishing Group
DOI: 10.1038/s41467-023-36660-4

<i>In situ</i> H₂O₂ Generation by Choline Oxidase and Its Application in Amino Polysaccharide Degradation by Coupling to Lytic Polysaccharide Monooxygenase

Autorzy: Nam‐Hai Hoang; Ole Golten; Zarah Forsberg; Vincent G. H. Eijsink; Michael Richter
Opublikowane w: ChemBioChem, Numer Volume 16, article e202300363, May 2023, 2023, ISSN 1439-4227
Wydawca: John Wiley & Sons Ltd.
DOI: 10.1002/cbic.202300363

Influence of ion mobility on the redox and catalytic properties of Cu ions in zeolites

Autorzy: Signorile, Matteo; Borfecchia, Elisa; Bordiga, Silvia; Berlier, Gloria
Opublikowane w: Chemical Science, Numer Numer 35, August 2022, 2022, Strona(/y) 10238-10250, ISSN 2041-6520
Wydawca: Royal Society of Chemistry
DOI: 10.1039/d2sc03565k

Thesis and dissertations (15)

Coupling of the organic linkers and their simultaneous integration in a missing linker UiO-66 

Autorzy: Laura Sypalyte
Opublikowane w: 2024
Wydawca: University of Oslo

Cu-based catalysts for C-H bond activation

Autorzy: Gabriele Deplano
Opublikowane w: 2023
Wydawca: University of Turin

Synthesis and Characterization of Metal Organic Frameworks Containing Bio inspired Cu-centers

Autorzy: Erlend Solbakken Aunan
Opublikowane w: 2024
Wydawca: University of Oslo

Mimicking the active site of Lytic Polysaccharides Monooxygenases (LPMO) enzymes for catalysisSynthesis and Characterization

Autorzy: Atiqa Ambrin Ansar
Opublikowane w: 2023
Wydawca: University of Oslo

Exploring the potential role of lytic polysaccharide monooxygenases from Bacillus licheniformis and Bacillus spizizenii in endospore germination

Autorzy: Ingeborg Langeby Korsane
Opublikowane w: 2024
Wydawca: NMBU

Synthesis of bioinspired bidentate N-ligands and their incorporation into UiO-67

Autorzy: Ingeborg Tangevold
Opublikowane w: 2024
Wydawca: University of Oslo

Investigating the role of aromatic core residues in protecting against oxidative damage in lytic polysaccharide monooxygenase SmAA10A

Autorzy: Moe, Trond
Opublikowane w: 2022
Wydawca: NMBU

The Impact of a Structurally Conserved Second Sphere Residue in Lytic Polysaccharide Monooxygenase Catalysis

Autorzy: Skaali, Rannei
Opublikowane w: 2022
Wydawca: NMBU

Bioinspired Copper Complexes for Incorporation into UiO-67

Autorzy: Isabelle Gerz
Opublikowane w: Numer Volume 2022, Numer 2536, 2022
Wydawca: University of Oslo

Synthesis and structural characterization of heteroleptic dipyridophenazine–based [Cu(N^N)(P^P)]+ complexes

Autorzy: Melchizedek Amoakwah
Opublikowane w: 2023
Wydawca: University of Oslo

Characterization of Zr-MOF containing anchored Cu species for C-H bond activation

Autorzy: Giuseppe Mastronardi
Opublikowane w: 2023
Wydawca: University of Turin

The roles of conserved second sphere residues in lytic polysaccharide monooxygenase catalysis

Autorzy: Mollatt, Maja
Opublikowane w: 2022
Wydawca: NMBU

Investigating the role of aromatic core residues in protecting against oxidative damage in lytic polysaccharide monooxygenase SmAA10A

Autorzy: Moe, Trond
Opublikowane w: 2023
Wydawca: NMBU

Synthesis and characterization of Ce/Zr mixed cluster Metal-Organic Frameworks UiO-67 as catalysts for the partial oxidation of cyclohexene

Autorzy: Federico Panagini
Opublikowane w: 2024
Wydawca: University of Turin

A multi-technique approach aimed at developing new Cu-based catalysts for C-H activations: from design, synthesis and characterization to evaluation of their performance

Autorzy: Barbara Centrella
Opublikowane w: 2024
Wydawca: University of Turin