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Unravelling the secrets of Cu-based catalysts for C-H activation

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Structural Elucidation, Aggregation, and Dynamic Behaviour of N,N,N,N-Copper(I) Schiff Base Complexes in Solid and in Solution: A Combined NMR, X-ray Spectroscopic and Crystallographic Investigation

Author(s): Isabelle Gerz, Dr. Sergio Augusto Venturinelli Jannuzzi, Dr. Knut T. Hylland, Dr. Chiara Negri, Dr. David S. Wragg, Dr. Sigurd Øien-Ødegaard, Prof. Mats Tilset, Prof. Unni Olsbye, Prof. Serena DeBeer, Prof. Mohamed Amedjkouh
Published in: European Journal of Inorganic Chemistry, 46, 2021, Page(s) 4762-4775, ISSN 1099-0682
Publisher: Wiley-VCH GmbH
DOI: 10.1002/ejic.202100722

Combining Valence-to-Core X-ray Emission and Cu K-edge X-ray Absorption Spectroscopies to Experimentally Assess Oxidation State in Organometallic Cu(I)/(II)/(III) Complexes

Author(s): Blaise L. Geoghegan; Yang Liu; Sergey Peredkov; Sebastian Dechert; Franc Meyer; Serena DeBeer; George E. Cutsail
Published in: Journal of the American Chemical Society, Volume 144, issue 6, January 2022, 2022, Page(s) 2520–2534, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.1c09505

Copper Pairing in the Mordenite Framework as a Function of the CuI/CuII Speciation

Author(s): Gabriele Deplano, Dr. Andrea Martini, Dr. Matteo Signorile, Dr. Elisa Borfecchia, Dr. Valentina Crocellà, Prof. Stian Svelle, Prof. Silvia Bordiga
Published in: Angewandte Chemie, 49, 2021, Page(s) 25891-25896, ISSN 1521-3757
Publisher: Wiley-VCH GmbH
DOI: 10.1002/anie.202109705

Titration of Cu(I) Sites in Cu-ZSM-5 by Volumetric CO Adsorption

Author(s): Gabriele Deplano, Matteo Signorile, Valentina Crocellà, Natale Gabriele Porcaro, Cesare Atzori, Bjørn Gading Solemsli, Stian Svelle, and Silvia Bordiga*
Published in: ACS Applied Materials & Interfaces, Volume 14, Issue 18, April 2022, 2022, Page(s) 21059–21068, ISSN 1944-8244
Publisher: American Chemical Society
DOI: 10.1021/acsami.2c03370

Investigating the role of Cu-oxo species in Cu-nitrate formation over Cu-CHA catalysts.

Author(s): Chiara Negri; Andrea Martini; Gabriele Deplano; Kirill A. Lomachenko; Ton V. W. Janssens; Elisa Borfecchia; Gloria Berlier; Silvia Bordiga
Published in: Physical Chemistry Chemical Physics, 23, 2021, Page(s) 18322-18337, ISSN 1463-9084
Publisher: The Royal Society of Chemistry
DOI: 10.1039/d1cp01754c

Towards a unified understanding of the copper sites in particulate methane monooxygenase: an X-ray absorption spectroscopic investigation

Author(s): George E. Cutsail; Matthew O. Ross; Amy C. Rosenzweig; Serena DeBeer
Published in: Chemical Science, 12, 2021, Page(s) 6194-6209, ISSN 2041-6539
Publisher: The Royal Society of Chemistry
DOI: 10.1039/d1sc00676b