Unravelling the secrets of Cu-based catalysts for C-H activation

Project Information

CUBE

Grant agreement ID: 856446

DOI

10.3030/856446

EC signature date 15 November 2019

Start date 1 May 2020

End date 31 October 2026

Funded under

• EXCELLENT SCIENCE - European Research Council (ERC)

Total cost

€ 9 885 989,13

EU contribution

€ 9 885 988,00

Coordinated by

UNIVERSITETET I OSLO
Norway

CORDIS provides links to public deliverables and publications of HORIZON projects.

Links to deliverables and publications from FP7 projects, as well as links to some specific result types such as dataset and software, are dynamically retrieved from OpenAIRE .

Publications

Peer reviewed articles (32)

X-ray absorption and emission spectroscopy of N₂S₂ Cu(<scp>ii</scp>)/(<scp>iii</scp>) complexes

Author(s): Blaise L. Geoghegan; Jessica K. Bilyj; Paul V. Bernhardt; Serena DeBeer; George E. Cutsail
Published in: Dalton Transactions, Issue 53, 2024, Page(s) 7828–7838, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/d4dt00085d

Structural Elucidation, Aggregation, and Dynamic Behaviour of N,N,N,N-Copper(I) Schiff Base Complexes in Solid and in Solution: A Combined NMR, X-ray Spectroscopic and Crystallographic Investigation

Author(s): Isabelle Gerz, Dr. Sergio Augusto Venturinelli Jannuzzi, Dr. Knut T. Hylland, Dr. Chiara Negri, Dr. David S. Wragg, Dr. Sigurd Øien-Ødegaard, Prof. Mats Tilset, Prof. Unni Olsbye, Prof. Serena DeBeer, Prof. Mohamed Amedjkouh
Published in: European Journal of Inorganic Chemistry, Issue 46, 2021, Page(s) 4762-4775, ISSN 1099-0682
Publisher: Wiley-VCH GmbH
DOI: 10.1002/ejic.202100722

Expanding the catalytic landscape of metalloenzymes with lytic polysaccharide monooxygenases

Author(s): Munzone A, Eijsink VGH, Berrin JG, Bissaro B
Published in: Nature Reviews Chemistry, Issue Volume 8, February 2024, 2024, Page(s) 106-119, ISSN 2397-3358
Publisher: Nature Springer
DOI: 10.1038/s41570-023-00565-z

Modulation of [CuOH/O]⁺ Properties in [2,2′-Bipyridine]₂ Homoleptic Complexes through Substitution at the 6,6’ Position by Methyl Groups

Author(s): Alessandro Damin; Matteo Bonomo; Barbara Centrella; Matteo Signorile; Claudia Barolo; Silvia Bordiga
Published in: ACS Omega, Issue Volume 9, Issue 14, 2024, Page(s) 16610−16620, ISSN 2470-1343
Publisher: American Chemical Society
DOI: 10.1021/acsomega.4c00598

Exploring Ce(IV)-MOFs redox behavior for catalysis by spectroscopies

Author(s): Valeria Finelli, Sergio Rojas-Buzo, Matteo Signorile, Francesca Bonino, Silvia Bordiga
Published in: Nano Materials Science, 2024, ISSN 2589-9651
Publisher: Elsevier B.V.
DOI: 10.1016/j.nanoms.2024.11.001

Synthesis of a mixed-linker Ce-UiO-67 metal–organic framework

Author(s): V. Finelli, G. Mastronardi, N. G. Porcaro, M. Signorile, F. Bonino, P. Á. Szilágyi, S. Bordiga
Published in: RSC Applied Interfaces, 2024, ISSN 2755-3701
Publisher: Royal Society of Chemistry
DOI: 10.1039/d4lf00278d

Ancestral sequence reconstruction as a tool to study the evolution of wood decaying fungi

Author(s): Iván Ayuso-Fernández; Gonzalo Molpeceres; Susana Camarero; Francisco Javier Ruiz-Dueñas; Angel T. Martínez
Published in: Frontiers in Fungal Biology, Issue Volume 3, article 1003489, 2022, ISSN 2673-6128
Publisher: Frontiers Media S.A.
DOI: 10.3389/ffunb.2022.1003489

Electrochemical Monitoring of Heterogeneous Peroxygenase Reactions Unravels LPMO Kinetics

Author(s): Lorenz Schwaiger; Florian Csarman; Hucheng Chang; Ole Golten; Vincent G. H. Eijsink; Roland Ludwig
Published in: ACS Catalysis, Issue Volume14, January 2024, 2024, Page(s) 1205−1219, ISSN 2155-5435
Publisher: American Chemical Society
DOI: 10.1021/acscatal.3c05194

Mutational dissection of a hole hopping route in a lytic polysaccharide monooxygenase (LPMO)

Author(s): Ivan Ayuso-Fernández, Tom Z. Emrich-Mills, Julia Haak, Ole Golten, Kelsi R. Hall, Lorentz Schwaiger, Trond S. Moe, Anton A. Stepnov, Roland Ludwig, Georg E. Cutsail III, Morten Sørlie, Åsmund Kjendseth Røhr, Vincent G. H. Eijsink
Published in: Nature Communications, Issue Volume 15, Article 3975, May 2024, 2024, ISSN 2041-1723
Publisher: Nature Publishing Group
DOI: 10.1038/s41467-024-48245-w

Copper(II)-Oxyl Formation in a Biomimetic Complex Activated by Hydrogen Peroxide: The Key Role of Trans-Bis(Hydroxo) Species

Author(s): Ning Cao, Abril C. Castro, David Balcells, Unni Olsbye, Ainara Nova
Published in: Inorganic Chemistry, Issue 63, 2024, Page(s) 23082-23094, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.4c01948

Combining Valence-to-Core X-ray Emission and Cu K-edge X-ray Absorption Spectroscopies to Experimentally Assess Oxidation State in Organometallic Cu(I)/(II)/(III) Complexes

Author(s): Blaise L. Geoghegan; Yang Liu; Sergey Peredkov; Sebastian Dechert; Franc Meyer; Serena DeBeer; George E. Cutsail
Published in: Journal of the American Chemical Society, Issue Volume 144, issue 6, January 2022, 2022, Page(s) 2520–2534, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.1c09505

Copper Pairing in the Mordenite Framework as a Function of the CuI/CuII Speciation

Author(s): Gabriele Deplano, Dr. Andrea Martini, Dr. Matteo Signorile, Dr. Elisa Borfecchia, Dr. Valentina Crocellà, Prof. Stian Svelle, Prof. Silvia Bordiga
Published in: Angewandte Chemie, Issue 49, 2021, Page(s) 25891-25896, ISSN 1521-3757
Publisher: Wiley-VCH GmbH
DOI: 10.1002/anie.202109705

Partial oxidation of cyclohexene over histidine-modified Cu-UiO-66 under aerobic conditions

Author(s): Erlend Aunan, Valeria Finelli, Sebastian Prodinger, Ning Cao, Beatrice Garetto, Gabriele Deplano, Peter Ng’ang’a Njoroge, Matteo Signorile, Elisa Borfecchia, Karl Petter Lillerud, Ainara Nova, Silvia Bordiga, Unni Olsbye
Published in: Journal of Catalysis, Issue 438, 2024, Page(s) 115722, ISSN 0021-9517
Publisher: Academic Press
DOI: 10.1016/j.jcat.2024.115722

Impact of the copper second coordination sphere on catalytic performance and substrate specificity of a bacterial LPMO

Author(s): Kelsi R. Hall, Maja Mollatt, Zarah Forsberg, Ole Golten, Lorenz Schwaiger, Roland Ludwig, Iván Ayuso-Fernández, Vincent G.H. Eijsink, Morten Sørlie
Published in: ACS Omega, Issue Volume 9, May 2024, 2024, Page(s) 23040-23052, ISSN 2470-1343
Publisher: American Chemical Society
DOI: 10.1021/acsomega.4c02666

Titration of Cu(I) Sites in Cu-ZSM-5 by Volumetric CO Adsorption

Author(s): Gabriele Deplano, Matteo Signorile, Valentina Crocellà, Natale Gabriele Porcaro, Cesare Atzori, Bjørn Gading Solemsli, Stian Svelle, and Silvia Bordiga*
Published in: ACS Applied Materials & Interfaces, Issue Volume 14, Issue 18, April 2022, 2022, Page(s) 21059–21068, ISSN 1944-8244
Publisher: American Chemical Society
DOI: 10.1021/acsami.2c03370

Cation-induced speciation of port-size during mordenite zeolite synthesis

Author(s): Sebastian Prodinger; Izar Capel Berdiell; Tomas Cordero-Lanzac; Odd Reidar Bygdnes; Bjørn Gading Solemsli; Karoline Kvande; Bjørnar Arstad; Pablo Beato; Unni Olsbye; Stian Svelle
Published in: Journal of Materials Chemistry A, Issue Volume 11, 2023, Page(s) 21884–21894, ISSN 2050-7488
Publisher: Royal Society of Chemistry
DOI: 10.1039/d3ta03444e

Reducibility of Cu-zeolites and stability of Cu+ monocarbonyl adducts: Qualitative and quantitative relationships from MCR-XAS and DFT

Author(s): Gabriele Deplano; Matteo Signorile; Cesare Atzori; Davide Salusso; Elisa Borfecchia; Valentina Crocellà; Silvia Bordiga
Published in: Catalysis Today, Issue Volume 427, 114403,, 2023, ISSN 0920-5861
Publisher: Elsevier BV
DOI: 10.1016/j.cattod.2023.114403

A Conserved Second Sphere Residue Tunes Copper Site Reactivity in Lytic Polysaccharide Monooxygenases

Author(s): Kelsi R. Hall; Chris Joseph; Iván Ayuso-Fernández; Ashish Tamhankar; Lukas Rieder; Rannei Skaali; Ole Golten; Frank Neese; Åsmund K. Røhr; Sergio A. V. Jannuzzi; Serena DeBeer; Vincent G. H. Eijsink; Morten Sørlie
Published in: Journal of the American Chemical Society, Issue Volume 145, pages 18888-18903, August 2023, 2023, ISSN 0002-7863
Publisher: American Chemical Society
DOI: 10.1021/jacs.3c05342

Investigating the role of Cu-oxo species in Cu-nitrate formation over Cu-CHA catalysts.

Author(s): Chiara Negri; Andrea Martini; Gabriele Deplano; Kirill A. Lomachenko; Ton V. W. Janssens; Elisa Borfecchia; Gloria Berlier; Silvia Bordiga
Published in: Physical Chemistry Chemical Physics, Issue 23, 2021, Page(s) 18322-18337, ISSN 1463-9084
Publisher: The Royal Society of Chemistry
DOI: 10.1039/d1cp01754c

Integrated Experimental and Theoretical Investigation of Copper Active Site Properties of a Lytic Polysaccharide Monooxygenase from Serratia marcescens

Author(s): Alessia Munzone, Manon Pujol, Ashish Tamhankar, Chris Joseph, Ievgen Mazurenko, Marius Réglier, Sergio A. V. Jannuzzi, Antoine Royant, Giuseppe Sicoli, Serena DeBeer, Maylis Orio, A. Jalila Simaan, and Christophe Decroos
Published in: Inorganic Chemistry, Issue Volume 63, Issue 24, 2024, Page(s) 11063-11078, ISSN 0020-1669
Publisher: American Chemical Society
DOI: 10.1021/acs.inorgchem.4c00602

Lytic polysaccharide monooxygenases: enzymes for controlled and site-specific Fenton-like chemistry

Author(s): B. Bissaro & V.G.H. Eijsink
Published in: Essays in Biochemistry, Issue Mar 18;Volume 67, issue 3, March 2023, 2023, Page(s) 575-584, ISSN 0071-1365
Publisher: Portland Press, Ltd.
DOI: 10.1042/ebc20220250

Reductants fuel lytic polysaccharide monooxygenase activity in a pH-dependent manner

Author(s): Ole Golten, Iván Ayuso-Fernández, Kelsi R. Hall, Anton A. Stepnov, Morten Sørlie, Åsmund Kjendseth Røhr, Vincent G. H. Eijsink
Published in: FEBS Letters, Issue Volume 597, Issue 10, 2023, Page(s) 1363-1374, ISSN 0014-5793
Publisher: Elsevier BV
DOI: 10.1002/1873-3468.14629

Understanding C–H activation in light alkanes over Cu-MOR zeolites by coupling advanced spectroscopy and temperature-programmed reduction experiments

Author(s): Karoline Kvande; Beatrice Garetto; Gabriele Deplano; Matteo Signorile; Bjørn Gading Solemsli; Sebastian Prodinger; Unni Olsbye; Pablo Beato; Silvia Bordiga; Stian Svelle; Elisa Borfecchia
Published in: Chemical Science, Issue August 2023, volume 14, 2023, Page(s) 9704–9723, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/d3sc01677c

A multi-technique approach to unveil the redox behaviour and potentiality of homoleptic CuI complexes based on substituted bipyridine ligands in oxygenation reactions

Author(s): Barbara Centrella; Gabriele Deplano; Alessandro Damin; Matteo Signorile; Mariagrazia Tortora; Claudia Barolo; Matteo Bonomo; Silvia Bordiga
Published in: Dalton Transactions, Issue Issue 51, July 2022, 2022, Page(s) 14439-14451, ISSN 1477-9234
Publisher: The Royal Society of Chemistry
DOI: 10.1039/d2dt01234k

"The ""life-span"" of lytic polysaccharide monooxygenases (LPMOs) correlates to the number of turnovers in the reductant peroxidase reaction"

Author(s): Kuusk S, Eijsink VGH, Väljamäe P.
Published in: Journal of Biological Chemistry, Issue Volume 299, Issue 9, Article 105094, Sep 2023, 2023, ISSN 1083-351X
Publisher: Elsevier BV
DOI: 10.1016/j.jbc.2023.105094

Reactivity of methoxy species towards methylation and oligomerization in Cu-zeolite systems

Author(s): Bjørn Gading Solemsli, Izar Capel Berdiell, Sebastian Prodinger, Karoline Kvande, Gabriele Deplano, Unni Olsbye, Pablo Beato, Silvia Bordiga, Stian Svelle
Published in: Catalysis Today, Issue Volume 436, Article 114729, 2024, ISSN 0920-5861
Publisher: Elsevier BV
DOI: 10.1016/j.cattod.2024.114729

Towards a unified understanding of the copper sites in particulate methane monooxygenase: an X-ray absorption spectroscopic investigation

Author(s): George E. Cutsail; Matthew O. Ross; Amy C. Rosenzweig; Serena DeBeer
Published in: Chemical Science, Issue 12, 2021, Page(s) 6194-6209, ISSN 2041-6539
Publisher: The Royal Society of Chemistry
DOI: 10.1039/d1sc00676b

Assessing the Influence of Zeolite Composition on Oxygen-Bridged Diamino Dicopper(II) Complexes in Cu-CHA DeNO_<i>x</i> Catalysts by Machine Learning-Assisted X-ray Absorption Spectroscopy

Author(s): Andrea Martini; Chiara Negri; Luca Bugarin; Gabriele Deplano; Reza K. Abasabadi; Kirill A. Lomachenko; Ton V. W. Janssens; Silvia Bordiga; Gloria Berlier; Elisa Borfecchia
Published in: The Journal of Physical Chemistry Letters, Issue Volume 13, Issue 26, July 2022, 2022, Page(s) 6164-6170, ISSN 1948-7185
Publisher: American Chemical Society
DOI: 10.1021/acs.jpclett.2c01107

Enabling a bioinspired <i>N</i>,<i>N</i>,<i>N</i>-copper coordination motif through spatial control in UiO-67: synthesis and reactivity

Author(s): Isabelle Gerz; Erlend S. Aunan; Valeria Finelli; Mouhammad Abu Rasheed; Gabriele Deplano; Rafael Cortez S. P.; Inga L. Schmidtke; David S. Wragg; Matteo Signorile; Knut T. Hylland; Elisa Borfecchia; Karl Petter Lillerud; Silvia Bordiga; Unni Olsbye; Mohamed Amedjkouh
Published in: Dalton Transactions, Issue Volume 53, 2024, Page(s) 8141-8153, ISSN 1477-9226
Publisher: Royal Society of Chemistry
DOI: 10.1039/d3dt03096b

Visible light-exposed lignin facilitates cellulose solubilization by lytic polysaccharide monooxygenases

Author(s): Eirik G. Kommedal; Camilla F. Angeltveit; Leesa J. Klau; Iván Ayuso-Fernández; Bjørnar Arstad; Simen G. Antonsen; Yngve Stenstrøm; Dag Ekeberg; Francisco Gírio; Florbela Carvalheiro; Svein J. Horn; Finn Lillelund Aachmann; Vincent G. H. Eijsink
Published in: Nature Communications, Issue Volume 14, article 1063, 2023, 2023, Page(s) 1-12, ISSN 2041-1723
Publisher: Nature Publishing Group
DOI: 10.1038/s41467-023-36660-4

<i>In situ</i> H₂O₂ Generation by Choline Oxidase and Its Application in Amino Polysaccharide Degradation by Coupling to Lytic Polysaccharide Monooxygenase

Author(s): Nam‐Hai Hoang; Ole Golten; Zarah Forsberg; Vincent G. H. Eijsink; Michael Richter
Published in: ChemBioChem, Issue Volume 16, article e202300363, May 2023, 2023, ISSN 1439-4227
Publisher: John Wiley & Sons Ltd.
DOI: 10.1002/cbic.202300363

Influence of ion mobility on the redox and catalytic properties of Cu ions in zeolites

Author(s): Signorile, Matteo; Borfecchia, Elisa; Bordiga, Silvia; Berlier, Gloria
Published in: Chemical Science, Issue Issue 35, August 2022, 2022, Page(s) 10238-10250, ISSN 2041-6520
Publisher: Royal Society of Chemistry
DOI: 10.1039/d2sc03565k

Thesis and dissertations (15)

Coupling of the organic linkers and their simultaneous integration in a missing linker UiO-66 

Author(s): Laura Sypalyte
Published in: 2024
Publisher: University of Oslo

Cu-based catalysts for C-H bond activation

Author(s): Gabriele Deplano
Published in: 2023
Publisher: University of Turin

Synthesis and Characterization of Metal Organic Frameworks Containing Bio inspired Cu-centers

Author(s): Erlend Solbakken Aunan
Published in: 2024
Publisher: University of Oslo

Mimicking the active site of Lytic Polysaccharides Monooxygenases (LPMO) enzymes for catalysisSynthesis and Characterization

Author(s): Atiqa Ambrin Ansar
Published in: 2023
Publisher: University of Oslo

Exploring the potential role of lytic polysaccharide monooxygenases from Bacillus licheniformis and Bacillus spizizenii in endospore germination

Author(s): Ingeborg Langeby Korsane
Published in: 2024
Publisher: NMBU

Synthesis of bioinspired bidentate N-ligands and their incorporation into UiO-67

Author(s): Ingeborg Tangevold
Published in: 2024
Publisher: University of Oslo

Investigating the role of aromatic core residues in protecting against oxidative damage in lytic polysaccharide monooxygenase SmAA10A

Author(s): Moe, Trond
Published in: 2022
Publisher: NMBU

The Impact of a Structurally Conserved Second Sphere Residue in Lytic Polysaccharide Monooxygenase Catalysis

Author(s): Skaali, Rannei
Published in: 2022
Publisher: NMBU

Bioinspired Copper Complexes for Incorporation into UiO-67

Author(s): Isabelle Gerz
Published in: Issue Volume 2022, Issue 2536, 2022
Publisher: University of Oslo

Synthesis and structural characterization of heteroleptic dipyridophenazine–based [Cu(N^N)(P^P)]+ complexes

Author(s): Melchizedek Amoakwah
Published in: 2023
Publisher: University of Oslo

Characterization of Zr-MOF containing anchored Cu species for C-H bond activation

Author(s): Giuseppe Mastronardi
Published in: 2023
Publisher: University of Turin

The roles of conserved second sphere residues in lytic polysaccharide monooxygenase catalysis

Author(s): Mollatt, Maja
Published in: 2022
Publisher: NMBU

Investigating the role of aromatic core residues in protecting against oxidative damage in lytic polysaccharide monooxygenase SmAA10A

Author(s): Moe, Trond
Published in: 2023
Publisher: NMBU

Synthesis and characterization of Ce/Zr mixed cluster Metal-Organic Frameworks UiO-67 as catalysts for the partial oxidation of cyclohexene

Author(s): Federico Panagini
Published in: 2024
Publisher: University of Turin

A multi-technique approach aimed at developing new Cu-based catalysts for C-H activations: from design, synthesis and characterization to evaluation of their performance

Author(s): Barbara Centrella
Published in: 2024
Publisher: University of Turin