Chiral separation of molecules enabled by enantioselective optical forces in integrated nanophotonic circuits

Informacje na temat projektu

CHIRALFORCE

Identyfikator umowy o grant: 101046961

DOI

10.3030/101046961

Projekt został zamknięty

Data podpisania przez KE 2 Sierpnia 2022

Data rozpoczęcia 1 Grudnia 2022

Data zakończenia 31 Maja 2026

Finansowanie w ramach

• The European Innovation Council (EIC)

Koszt całkowity

€ 3 263 726,25

Wkład UE

€ 3 263 726,25

Koordynowany przez

UNIVERSITAT POLITECNICA DE VALENCIA
Spain

CORDIS oferuje możliwość skorzystania z odnośników do publicznie dostępnych publikacji i rezultatów projektów realizowanych w ramach programów ramowych HORYZONT.

Odnośniki do rezultatów i publikacji związanych z poszczególnymi projektami 7PR, a także odnośniki do niektórych konkretnych kategorii wyników, takich jak zbiory danych i oprogramowanie, są dynamicznie pobierane z systemu OpenAIRE .

Rezultaty

Documents, reports (11)

Synthesis and optimization of chiral polymerized liquid crystal nanoparticles

We will describe the mechanisms to synthesize and optimize chiral polymerized liquid crystal nanoparticles that will be used in experiments in WP1 and later in WP3 (for separation purposes)

Synthesis and optimization of chiral nanoparticles

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Data management plan 2

Definition of the revised Data Management Plan

Report on optical force and enantiomer resolving power predictions for the integrated waveguide designs to guide the demonstrator

In WP2 we will perform calculations on optical force and enantiomer resolving power in chiral integrated waveguides. Such calculations, which will be reported in this deliverable, will lead to designs to guide the final demonstrator.

Optimized building blocks: waveguides, interfaces, compensators

Key building blocks of C-PICs (waveguides, interfaces, compensators) will be designed and optimized using numerical simulations. Here we will report on such designs to be later fabricated to form c-PICs.

Report on preliminary results and algorithm of numerical DFT method to determine chirality spectra of molecules, and its link with optical force calculations

Here we will describe the first results as well as the numerical DFT method employed to determine the chirality spectra of molecules. We will also establish a link so that such molecules can be used in the optical force calculations to be performed in WP2.

Scientific and Technical review documents RP1

The draft agenda and presentations to be delivered during the 1st review meeting

Data management plan 1

Definition of the Data Management Plan

Scientific and Technical review documents RP2

The draft agenda and presentations to be delivered during the 2nd review meeting

Dissemination and Exploitation Plan 1

Definition of the Dissemination and Exploitation Plan

Risks, bottlenecks and opportunities of enantioselective optical forces

First simulation results on optical forces exerted by chiral modes in integrated waveguides will allow us to establish the risks, bottlenecks, and opportunities of enantioselective optical forces. These results will set the limits of the application of the CHIRALFORCE technology.

Websites, patent fillings, videos etc. (2)

Creation of online open database of chiral polarizability of molecules/particles populated with our broadband calculations on various molecules and particles

From all the simulation and modeling results performed within WP1 to get the chiral response of molecules and nanoparticles, we will create an online open database of chiral polarizability of molecules/particles. This database will be useful in CHIRALFORCE as well as for any researcher interested in chiral matter and chiroptical interaction.

Project website

Development and operation of the project’s website

Publikacje

Peer reviewed articles (13)

Chiral longitudinal forces in dielectric photonic waveguides

Autorzy: Martínez-Romeu Josep; Diez Iago; Golat Sebastian; Rodríguez-Fortuño Francisco J.; Martínez Alejandro
Opublikowane w: EPJ Web of Conferences, Numer Vol 309, 2024, ISSN 2100-014X
Wydawca: EDP Sciences
DOI: 10.1051/EPJCONF/202430901004

Chiral optical forces in a slot waveguide for the separation of molecules in gas

Autorzy: Josep Martínez-Romeu, Daniel Arenas-Ortega, Iago Diez, Alejandro Martínez
Opublikowane w: Optics Letters, Numer 51, 2026, ISSN 0146-9592
Wydawca: Optica Publishing Group
DOI: 10.1364/OL.575264

Optical dipolar chiral sorting forces and their manifestation in evanescent waves and nanofibers

Autorzy: Sebastian Golat, Jack J. Kingsley-Smith, Iago Diez, Josep Martinez-Romeu, Alejandro Martínez, and Francisco J. Rodríguez-Fortuño
Opublikowane w: Physical Review Research, Numer Vol. 6, Iss. 2 — April - June 2024, 2024, ISSN 2643-1564
Wydawca: American Physical Society
DOI: 10.48550/arxiv.2310.11272

On-chip chiroptical sensor based on directional deflection of light: a Stern–Gerlach integrated optical analog [Invited]

Autorzy: Josep Martínez-Romeu, Alejandro Martínez, J. Enrique Vázquez-Lozano
Opublikowane w: Journal of the Optical Society of America B, Numer 43, 2026, ISSN 0740-3224
Wydawca: Optica Publishing Group
DOI: 10.1364/JOSAB.596711

E. coli filament buckling modulates Min patterning and cell division

Autorzy: Marta Nadal, Léna Guitou, Iago Diez, Juan Hurtado, Alejandro Martínez, Iago Grobas, Javier Buceta
Opublikowane w: Nature Communications, Numer 16, 2025, ISSN 2041-1723
Wydawca: Springer Science and Business Media LLC
DOI: 10.1038/S41467-025-63509-9

Longitudinal chiral forces in photonic integrated waveguides to separate particles with realistically small chirality

Autorzy: Josep Martínez-Romeu, Iago Diez, Sebastian Golat, Francisco J. Rodríguez-Fortuño and Alejandro Martínez
Opublikowane w: Nanophotonics, Numer Vol.13, nº 23, 2024, ISSN 2192-8614
Wydawca: de Gruyter
DOI: 10.1515/NANOPH-2024-0339

Chiral forces in longitudinally invariant dielectric photonic waveguides

Autorzy: Alejandro Martinez; Francisco Rodríguez-Fortuño; Sebastian Golat; Iago Diez; Josep Martinez-Romeu
Opublikowane w: Photonics Research, Numer Vol.12, Numer, pp.431-443, 2024, ISSN 2327-9125
Wydawca: Optica Publishing Group
DOI: 10.48550/arXiv.2310.16413

Chiral Self-assembly of Zinc and Magnesium Porphyrins with Enantiopure Cyclohexanohemicucurbiturils in Solution and in Solid-State

Autorzy: Marko Šakarašvili; Khai-Nghi Truong; Lukáš Ustrnul; Nele Konrad; Kristjan Siilak; Tatsiana Burankova; Reiko Kuroda; Mathias O. Senge; Victor Borovkov; Jas S. Ward; Kari Rissanen; Riina Aav
Opublikowane w: Inorganic Chemistry, Numer Vol 64- Numer 48, 2025, ISSN 1520-510X
Wydawca: ACS Publications
DOI: 10.1021/ACS.INORGCHEM.5C04969

A decomposition of light’s spin angular momentum density

Autorzy: Alex J. Vernon; Sebastian Golat; Claire Rigouzzo; Eugene A. Lim; Francisco J. Rodríguez-Fortuño
Opublikowane w: Light: Science & Applications, Vol 13, Iss 1, Pp 1-12 (2024), Numer 13, 2024, ISSN 2047-7538
Wydawca: Springer Nature Ltd.
DOI: 10.48550/arxiv.2310.03804

Chirality transfer from penicillamine to gold nanoparticles enables enantioselective electrochemical sensing of cysteine

Autorzy: Bahar Atik, Anupa Kumari, Christos Englezos, Melih Ögeday Cicek, Francisco Ruiz-Zepeda, Georgios Katsoukis, Wilfred G. van der Wiel, Oluwafemi Stephen Ojambati, Arturo Susarrey-Arce, Han Gardeniers
Opublikowane w: Nanoscale, 2026, ISSN 2040-3364
Wydawca: Royal Society of Chemistry (RSC)
DOI: 10.1039/D6NR01490A

The electromagnetic symmetry sphere: a framework for energy, momentum, spin and other electromagnetic quantities

Autorzy: Sebastian Golat; Alex J Vernon; Francisco J Rodríguez-Fortuño
Opublikowane w: Physica Scripta, 2025, ISSN 1402-4896
Wydawca: IOP Publishing
DOI: 10.48550/ARXIV.2405.15718

Creating tunable lateral optical forces through multipolar interplay in single nanowires

Autorzy: Fan Nan, Francisco J. Rodríguez-Fortuño, Shaohui Yan, Jack J. Kingsley-Smith, Jack Ng, Baoli Yao, Zijie Yan & Xiaohao Xu
Opublikowane w: Nature Communications, Numer 14, number 6361, 2023, ISSN 2041-1723
Wydawca: Nature Publishing Group
DOI: 10.1038/S41467-023-42076-X

A Rational Framework to Estimate the Chiroptical Activity of [6]Helicene Derivatives

Autorzy: Mirko Vanzan, Susanna Bertuletti, Giacomo Becatti, Belen Bazan, Minze T. Rispens, Steven I. C. Wan, Michel Leeman, Willem L. Noorduin, Francesca Baletto
Opublikowane w: The Journal of Physical Chemistry A, Numer 129, 2025, ISSN 1089-5639
Wydawca: American Chemical Society (ACS)
DOI: 10.1021/ACS.JPCA.5C04360