With this project, an experimental methodology that allows the comprehensive evaluation of the performance of a catalytic system under real operation conditions and gain fundamental understanding about the chemical reaction, the catalyst and the reactor thermal behaviour, was set. This methodology is presented as a useful tool not only for those working specifically on oxidative coupling of methane but also for those dealing with elucidating reaction mechanisms and intrinsic kinetics for complex chemical reactions. With this holistic approach a rational design of catalytic systems suitable for a specific reactor configuration is feasible. Furthermore, accurate kinetic models describing the process under more realistic conditions can be developed.
Developing effective catalysts and, thus, making chemical processes more sustainable and efficient are the key aspects to reach European Green Deal objectives. This project looks into chemical processes from a holistic perspective, aiming to gain understanding of them under closer to industry application conditions and rationalize the catalyst design based on experimental observations. More specifically, this project deals with methane activation to useful chemical processes, aiming to reduce oil dependency, providing alternative synthesis routes for key chemicals, such as hydrogen and ethylene. The successful execution of this diversification of chemicals and fuels production relays on efficient use of energy as well. For this aim, microwave-assisted reactors are investigated in this project, which can run under green electricity, in alignment with the REPowerEU goals and the electrification of chemical industry.