Descrizione del progetto
Riciclare il biocarbonio in precursori utili
Il biocarbonio è una risorsa rinnovabile, abbondante e non tossica. Il progetto D-Carbonize, finanziato dall’UE, consentirà di riciclare il biocarbonio in preziosi materiali precursori per le industrie chimiche e dei polimeri. L’utilizzo di nuovi catalizzatori metallici e organocatalizzatori per la conversione di biocarbonio in monomeri e polimeri consentirà di creare sostanze chimiche quali carbonati, carbammati, acidi carbossilici, esteri, sintoni farmaceutici e polimeri basati sulla biomassa/CO2. Avvalendosi della catalisi per la valorizzazione del biocarbonio, il progetto offrirà la possibilità di creare poliesteri, carbonati e amidi per innovativi materiali su misura. D-Carbonize esplorerà inoltre metodi di depolimerizzazione per il riciclo di polimeri sintetici. Nel corso del progetto, saranno formati 12 dottorandi.
Obiettivo
D-Carbonize´s approach targets biocarbon recycling into valuable starting materials for the chemical/polymer industries and will primarily provide innovative low-carb catalysis solutions. The use of biocarbon is advantageous in many respects as it is renewable, generally abundant and non-toxic, and it represents easy-to-handle carbon reagents even on larger scale. Despite the lack of universal (catalytic) strategies available for biocarbon valorization into monomers and polymers, recent advances in catalysis science have demonstrated the engineering and use of new promising metal- and organo-catalysts with high potential to overcome these limitations, thereby creating the necessary feasibility to transform biocarbon into (1) fine chemicals such as carbonates, carbamates, carboxylic acids, and esters, (2) pharmaceutical synthons, and (3) biomass/CO2-based polymers. Thus, catalysis has already been shown to be a useful technology for biocarbon valorization but has been rarely used in the wider context of new and functional biocarbon based monomer/polymer development. The use of the latter helps to shape the future of functionalized poly-esters/carbonates/amides and their subsequent utilization in novel tailor-made and commercially relevant materials. Furthermore, this project will also explore depolymerization pathways to recycle the synthesized polymers obtaining new monomers and/or other added-value molecules that could re-enter the loop and be used in new polymers and materials. The network will recruit 12 doctoral candidates, who will be awarded double doctoral degrees by two universities in two different countries at the end of the training program. D-Carbonize brings together leading high-education institutions, research centers and companies to form an innovation community able to offer excellent research and training both in R&D and entrepreneurship.
Campo scientifico
- natural scienceschemical sciencesorganic chemistryorganic acids
- social scienceseconomics and businessbusiness and managemententrepreneurship
- natural scienceschemical sciencesinorganic chemistryinorganic compounds
- natural scienceschemical sciencespolymer sciences
- natural scienceschemical sciencescatalysis
Parole chiave
Programma(i)
- HORIZON.1.2 - Marie Skłodowska-Curie Actions (MSCA) Main Programme
Meccanismo di finanziamento
HORIZON-TMA-MSCA-DN-JD - HORIZON TMA MSCA Doctoral Networks - Joint DoctoratesCoordinatore
43007 Tarragona
Spagna