Cel Wetlands store between 15 and 30% of the global soil carbon pool as dissolved and particulate organic matter (DOM and POM). Wetlands are also the largest natural source of atmospheric methane (CH4) and given the high warming potential of CH4, formation and loss processes of CH4 in wetlands have received considerable research interest. Yet, our understanding of methanogenesis in wetlands is incomplete. Recent studies have implicated DOM and POM in two processes that suppress methanogenesis in wetlands. The first is utilization of DOM and POM as terminal electron acceptors (TEAs) in anaerobic microbial respiration. Electron transfer to OM is thought to competitively suppress methanogenesis. The second process is the direct inhibition of methanogens by polyphenolic DOM constituents. The goal of the proposed research is to quantify the importance of these two processes by incubating natural wetland samples in the laboratory and selectively perturbing them to study the two processes. The importance of DOM and POM as TEAs will be assessed by quantifying changes in their redox states during anoxic incubations using analytical electrochemistry combined with monitoring the formation of CH4 and carbon dioxide. Incubation experiments with alternating anoxic and oxic conditions will be carried out to determine whether electron transfer to OM samples is reversible and, thus, whether suppression of methanogenesis via this process is sustained over repeated redox cycles in periodically anoxic wetlands. The potential inhibitory effects of polyphenolic DOM on methanogens will be assessed by measuring changes in methanogenesis in anoxic samples after addition of both natural and model polyphenols. The proposed research will derive a mechanistic understanding of the two studied processes. This understanding will allow transfer of the results from the lab-scale investigations to processes at the field scale and will help to improve wetland management policies. Dziedzina nauki natural scienceschemical scienceselectrochemistrynatural scienceschemical sciencesorganic chemistryaliphatic compounds Program(-y) FP7-PEOPLE - Specific programme "People" implementing the Seventh Framework Programme of the European Community for research, technological development and demonstration activities (2007 to 2013) Temat(-y) FP7-PEOPLE-2013-IIF - Marie Curie Action: "International Incoming Fellowships" Zaproszenie do składania wniosków FP7-PEOPLE-2013-IIF Zobacz inne projekty w ramach tego zaproszenia System finansowania MC-IIF - International Incoming Fellowships (IIF) Koordynator EIDGENOESSISCHE TECHNISCHE HOCHSCHULE ZUERICH Wkład UE € 207 928,80 Adres Raemistrasse 101 8092 Zuerich Szwajcaria Zobacz na mapie Region Schweiz/Suisse/Svizzera Zürich Zürich Rodzaj działalności Higher or Secondary Education Establishments Kontakt administracyjny Kristopher Mcneill (Prof.) Linki Kontakt z organizacją Opens in new window Strona internetowa Opens in new window Koszt całkowity Brak danych