Water Forced in Hydrophobic Nano-Confinement: Tunable Solvent System

Publikacje

Engineering of Phenylpyridine- and Bipyridine-Based Covalent Organic Frameworks for Photocatalytic Tandem Aerobic Oxidation/Povarov Cyclization

Autorzy: Maarten Debruyne; Sander Borgmans; Sambhu Radhakrishnan; Eric Breynaert; Henk Vrielinck; Karen Leus; Andreas Laemont; Juul De Vos; Kuber Singh Rawat; Siebe Vanlommel; Hannes Rijckaert; Hadi Salemi; Jonas Everaert; Flore Vanden Bussche; Dirk Poelman; Rino Morent; Nathalie De Geyter; Pascal Van Der Voort; Veronique Van Speybroeck; Christian V. Stevens
Opublikowane w: ACS Applied Materials & Interfaces, Numer Vol. 15; iss. 29, 2023, Strona(/y) 35092-35106, ISSN 1944-8244
Wydawca: American Chemical Society
DOI: 10.1021/acsami.3c07036

Hierarchical COK-X Materials for Applications in Catalysis and Adsorptive Separation and Controlled Release

Autorzy: Sreeprasanth Pulinthanathu Sree, Eric Breynaert, Christine E. A. Kirschhock and Johan A. Martens
Opublikowane w: Frontiers in Chemical Engineering, Numer 26732718, 2022, ISSN 2673-2718
Wydawca: Frontiers Research Foundation
DOI: 10.3389/fceng.2022.810443

Non-Isothermal Kinetic Model of Water Vapor Adsorption on a Desiccant Bed for Harvesting Water from Atmospheric Air

Autorzy: Peeters R, Verbruggen V, Ronge J, Martens JA
Opublikowane w: Industrial & Engineering Chemistry Research, Numer Vol. 60, Iss. 31, 2021, Strona(/y) 11812-11823, ISSN 0888-5885
Wydawca: American Chemical Society
DOI: 10.1021/acs.iecr.1c01733

Structure I methane hydrate confined in C8-grafted SBA-15: A highly efficient storage system enabling ultrafast methane loading and unloading

Autorzy: Emile Jules Beckwée; Maarten Houlleberghs; Radu-George Ciocarlan; C. Vinod Chandran; Sambhu Radhakrishnan; Lucas Hanssens; Pegie Cool; Johan Martens; Eric Breynaert; Gino V. Baron; Joeri F.M. Denayer
Opublikowane w: Applied Energy, Numer Vol. 353, Numer A, 2024, ISSN 0306-2619
Wydawca: Pergamon Press Ltd.
DOI: 10.1016/j.apenergy.2023.122120

Long-term Generation of Longitudinal Spin Order Controlled by Ammonia Ligation Enables Rapid SABRE Hyperpolarized 2D NMR

Autorzy: Vaneeckhaute E, De Ridder S, Tyburn J-M, Kempf J, Taulelle F, Martens J, Breynaert E
Opublikowane w: Chemphyschem, Numer Vol. 22, Iss. 12, 2021, Strona(/y) 1170-1177, ISSN 1439-4235
Wydawca: John Wiley & Sons Ltd.
DOI: 10.1002/cphc.202100079

Interfacial study of clathrates confined in reversed silica pores

Autorzy: Mileo, Paulo G. M.; Rogge, Sven M. J.; Houlleberghs, Maarten; Breynaert, Eric; Martens, Johan A.; Van Speybroeck, Veronique
Opublikowane w: Journal of Materials Chemistry A, Numer 4, 2021, ISSN 2050-7488
Wydawca: Royal Society of Chemistry
DOI: 10.1039/d1ta03105h

Hyperpolarised Magnetic Resonance of Exchangeable Protons Using Parahydrogen and Aminosilane

Autorzy: Ewoud Vaneeckhaute, J Tyburn, D Kilgour, JG Kempf, Francis Taulelle, Johan A Martens, Eric Breynaert
Opublikowane w: The Journal of Physical Chemistry C: Energy Conversion and Storage, Optical and Electronic Devices, Interfaces, Nanomaterials, and Hard Matter, Numer Vol. 124; iss. 27, 2020, Strona(/y) 14541 - 14549, ISSN 1932-7447
Wydawca: American Chemical Society
DOI: 10.1021/acs.jpcc.0c01149

Magneto-Hydrodynamic Mixing: a New Technique for Preparing Carbomer Hydrogels

Autorzy: Maarten Houlleberghs,Loes Verheyden,Filip Voorspoels,C. Vinod Chandran,Karel Duerinckx,Sambhu Radhakrishnan,Johan A. Martens,Eric Breynaert
Opublikowane w: AIChE journal, Numer 00011541, 2022, ISSN 0001-1541
Wydawca: American Institute of Chemical Engineers
DOI: 10.1002/aic.17911

Hydrogen-Bonded Water-Aminium Assemblies for Synthesis of Zeotypes with Ordered Heteroatoms

Autorzy: Park, S. H.; Radhakrishnan, S.; Choi, W.; Chandran, C. V.; Kemp, K. C.; Breynaert, E.; Bell, R. G.; Kirschhock, C. E. A.; Hong, S. B.
Opublikowane w: Journal Of The American Chemical Society, Numer 00027863, 2022, Strona(/y) 18054–18061, ISSN 0002-7863
Wydawca: American Chemical Society
DOI: 10.1021/jacs.2c07661

Nucleation of Porous Crystals from Ion-Paired Prenucleation Clusters

Autorzy: Nick Pellens; Nikolaus Doppelhammer; Sambhu Radhakrishnan; Karel Asselman; C. Vinod Chandran; Dries Vandenabeele; Bernhard Jakoby; Johan A. Martens; Francis Taulelle; Erwin K. Reichel; Eric Breynaert; Christine E. A. Kirschhock
Opublikowane w: Chemistry of Materials, Numer 08974756, 2022, Strona(/y) 7139–7149, ISSN 0897-4756
Wydawca: American Chemical Society
DOI: 10.1021/acs.chemmater.2c00418

Illuminating the Black Box: A Perspective on Zeolite Crystallization in Inorganic Media

Autorzy: Karel Asselman; Christine Kirschhock; Eric Breynaert
Opublikowane w: Accounts of Chemical Research, Numer Vol. 56, 2023, Strona(/y) 2391-2402, ISSN 0001-4842
Wydawca: American Chemical Society
DOI: 10.1021/acs.accounts.3c00269

Absolute Quantification of Residual Solvent in Mesoporous Silica Drug Formulations Using Magic-Angle Spinning NMR Spectroscopy

Autorzy: Hannah Vanderschaeghe; Maarten Houlleberghs; Loes Verheyden; Dirk Dom; C. Vinod Chandran; Sambhu Radhakrishnan; Johan A. Martens; Eric Breynaert
Opublikowane w: Analytical Chemistry, Numer Vol. 95; iss. 3, 2023, Strona(/y) 1880-1887, ISSN 0003-2700
Wydawca: American Chemical Society
DOI: 10.1021/acs.analchem.2c03646

Dispersing carbomers, mixing technology matters!

Autorzy: Houlleberghs, Maarten; Verheyden, Loes; Voorspoels, Filip; Chandran, C. Vinod; Duerinckx, Karel; Radhakrishnan, Sambhu; Martens, Johan; Breynaert, Eric
Opublikowane w: RSC Advances, Numer vol 12, Iss. 13, 2022, Strona(/y) 7830 - 7834, ISSN 2046-2069
Wydawca: Royal Society of Chemistry
DOI: 10.1039/d2ra00176d

Eu3+ doped ZnAl layered double hydroxides as calibrationless, fluorescent sensors for carbonate

Autorzy: Alysson F. Morais; Ivan G. N. Silva; Bruno J. Ferreira; Alexandre C. Teixeira; Sreeprasanth P. Sree; Huayna Terraschke; Fernando A. Garcia; Eric Breynaert; Danilo Mustafa
Opublikowane w: Chemical Communications, Numer Vol. 59, 2023, Strona(/y) 13571-13574, ISSN 1359-7345
Wydawca: Royal Society of Chemistry
DOI: 10.1039/d3cc03066k

A zeolite crystallisation model confirmed by in-situ observation.

Autorzy: Nick Pellens, Nikolaus Doppelhammer, Karel Asselman, Barbara Thijs, Bernhard Jakoby, Erwin K. Konrad Reichel, Francis Taulelle, Johan Martens, Eric Breynaert and Christine Kirschhock
Opublikowane w: Faraday Discussions, Numer accepted, 2022, Strona(/y) https://lirias.kuleuven.be/handle/20.500.12942/694201, ISSN 1359-6640
Wydawca: Royal Society of Chemistry
DOI: 10.1039/d1fd00093d

A Pyrrolidine Functionalized Poly[(Ethylene Glycol) Methacrylate] Resin as a Heterogeneous Catalyst for Aqueous Aldol Reactions

Autorzy: Bert Biesemans; Noor Aljammal; Sambhu Radhakrishnan; Eric Breynaert; Christian V. Stevens; Jeroen Lauwaert; Joris W. Thybaut
Opublikowane w: Catalysts, Numer Vol. 12; iss. 11, 2022, ISSN 2073-4344
Wydawca: Multidisciplinary Digital Publishing Institute (MDPI)
DOI: 10.3390/catal12111389

Building a Cost-Efficient High-Pressure Cell for Online High-Field NMR and MRI Using Standard Static Probe Heads: An In Situ Demonstration on Clathrate Hydrate Formation

Autorzy: Maarten Houlleberghs; Shannon Helsper; Dirk Dom; Thierry Dubroca; Bianca Trociewitz; Robert W. Schurko; Sambhu Radhakrishnan; Eric Breynaert
Opublikowane w: Analytical Chemistry, Numer Vol. 95; iss. 46, 2023, Strona(/y) 16936–16942, ISSN 0003-2700
Wydawca: American Chemical Society
DOI: 10.1021/acs.analchem.3c03050

A Porous POSiSil Suited for Pressure-Driven Reversible Confinement of Solutions: PSS-2

Autorzy: Sam Smet; Pieter Verlooy; Sreeprasanth Pulinthanathu; Christine Kirschhock; Francis Taulelle; Eric Breynaert
Opublikowane w: Chemistry-A European Journal, Numer Vol. 25; iss. 56, 2019, Strona(/y) 12957-12965, ISSN 0947-6539
Wydawca: John Wiley & Sons Ltd.
DOI: 10.1002/chem.201901913

Framework flexibility-driven CO2 adsorption on a zeolite

Autorzy: Hyun June Choi, Jung Gi Min, Sang Hyun Ahn, Jiho Shin, Suk Bong Hong, Sambhu Radhakrishnan, Vinod C Chandran, Robert G Bell, Eric Breynaert, Christine EA Kirschhock
Opublikowane w: Materials Horizons, Numer Vol. 7; iss. 6, 2020, Strona(/y) 1528 - 1532, ISSN 2051-6347
Wydawca: ROYAL SOCIETY OF CHEMISTRY
DOI: 10.1039/d0mh00307g

Hydrogen Clathrates: Next Generation Hydrogen Storage Materials

Autorzy: Gupta A, Baron GV, Perreault P, Lenaerts S, Ciocarlan R, Cool P, Mileo PGM, Rogge S, Van Speybroeck V, Watson G, Van Der Voort P, Houlleberghs M, Breynaert E, Martens J, Denayer JFM
Opublikowane w: Energy Storage Materials, Numer Vol. 41, 2021, Strona(/y) 69-107, ISSN 2405-8297
Wydawca: Elsevier
DOI: 10.1016/j.ensm.2021.05.044

Isotopological Fingerprinting Using 1H/D Scrambling Identifies the Stereochemistry of Hyperpolarization Catalysts Transferring Spin Polarization from Parahydrogen to Substrates Using Signal Amplification by Reversible Exchange

Autorzy: Ewoud Vaneeckhaute; Jean-Max Tyburn; James G. Kempf; Johan A. Martens; Eric Breynaert
Opublikowane w: Journal of Physical Chemistry Letters, Numer 19487185, 2022, Strona(/y) 3516-3522, ISSN 1948-7185
Wydawca: American Chemical Society
DOI: 10.1021/acs.jpclett.2c00185

RHO Zeolites with High Hydrothermal Stability

Autorzy: Hannelore Geerts-Claes; Gina Vanbutsele; Sreeprasanth Pulinthanathu Sree; Sambhu Radhakrishnan; C. Vinod Chandran; Eric Breynaert; Johan A. Martens; Sam Smet
Opublikowane w: Crystal Growth & Design, Numer Vol. 23; iss. 11, 2023, Strona(/y) 7829-7840, ISSN 1528-7483
Wydawca: American Chemical Society
DOI: 10.1021/acs.cgd.3c00643

Super-ions of sodium cations with hydrated hydroxide anions: inorganic structure-directing agents in zeolite synthesis

Autorzy: Asselman K, Pellens N, Radhakrishnan S, Chandran CV, Martens JA, Taulelle F, Verstraelen T, Hellström M, Breynaert E, Kirschhock CEA
Opublikowane w: Materials Horizons, Numer Vol. 8, Iss. 9, 2021, Strona(/y) 2576-2583, ISSN 2051-6347
Wydawca: The Royal Society of Chemistry
DOI: 10.1039/d1mh00733e

Ion-Pairs in Aluminosilicate-Alkali Synthesis Liquids Determine the Aluminum Content and Topology of Crystallizing Zeolites

Autorzy: Karel Asselman; Nick Pellens; Barbara Thijs; Nikolaus Doppelhammer; Mohamed Haouas; Francis Taulelle; Johan A. Martens; Eric Breynaert; Christine E.A. Kirschhock
Opublikowane w: Chemistry of Materials, Numer 08974756, 2022, Strona(/y) 7150-7158, ISSN 0897-4756
Wydawca: American Chemical Society
DOI: 10.1021/acs.chemmater.2c00773

Prediction of Cu Zeolite NH3-SCR Activity from Variable Temperature 1H NMR Spectroscopy

Autorzy: Sambhu Radhakrishnan; Sam Smet; C. Vinod Chandran; Sreeprasanth Pulinthanathu Sree; Karel Duerinckx; Gina Vanbutsele; Johan A. Martens; Eric Breynaert
Opublikowane w: Molecules, Numer Vol. 28; iss. 18, 2023, ISSN 1420-3049
Wydawca: Multidisciplinary Digital Publishing Institute (MDPI)
DOI: 10.3390/molecules28186456

Fresh water production from atmospheric air: Technology and innovation outlook

Autorzy: Robin Peeters, Hannah Vanderschaeghe, Jan Rongé, Johan A. Martens
Opublikowane w: iScience, Numer 25890042, 2021, Strona(/y) 103266-103266, ISSN 2589-0042
Wydawca: elsevier inc.
DOI: 10.1016/j.isci.2021.103266

Does Water Enable Porosity in Aluminosilicate Zeolites? Porous Frameworks versus Dense Minerals

Autorzy: Karel Asselman; Mohamed Haouas; Maarten Houlleberghs; Sambhu Radhakrishnan; Wauter Wangermez; Christine E. A. Kirschhock; Eric Breynaert
Opublikowane w: Crystal Growth & Design, Numer Vol. 23; iss. 5, 2023, Strona(/y) 3338-3348, ISSN 1528-7483
Wydawca: American Chemical Society
DOI: 10.1021/acs.cgd.2c01476

Structural Aspects Affecting Phase Selection in Inorganic Zeolite Synthesis

Autorzy: Karel Asselman; Dries Vandenabeele; Nick Pellens; Nikolaus Doppelhammer; Christine E.A. Kirschhock; Eric Breynaert
Opublikowane w: Chemistry of Materials, Numer Vol. 34; iss. 24, 2022, Strona(/y) 11081-11092, ISSN 0897-4756
Wydawca: American Chemical Society
DOI: 10.1021/acs.chemmater.2c03204

Water as a tuneable solvent: a perspective

Autorzy: Eric Breynaert, Maarten Houlleberghs, Sambhu Radhakrishnan, Gerhard Grübel, Francis Taulelle, Johan A. Martens
Opublikowane w: Chemical Society Reviews, 2020, ISSN 0306-0012
Wydawca: Royal Society of Chemistry
DOI: 10.1039/c9cs00545e

Energy performance and climate dependency of technologies for fresh water production from atmospheric water vapour

Autorzy: Robin Peeters, Hannah Vanderschaeghe, Jan Rongé, Johan A Martens,
Opublikowane w: Environmental Science-Water Research & Technology, Numer Vol. 6, iss. 8, 2020, Strona(/y) 2016-2034, ISSN 2053-1419
Wydawca: Royal Society of Chemistry
DOI: 10.1039/d0ew00128g

Noncontact In Situ Multidiagnostic NMR/Dielectric Spectroscopy

Autorzy: Alysson F. Morais; Sambhu Radhakrishnan; Gavriel Arbiv; Dirk Dom; Karel Duerinckx; C. Vinod Chandran; Johan A. Martens; Eric Breynaert
Opublikowane w: Analytical Chemistry, Numer Vol. 96; iss. 13, 2024, Strona(/y) 5071-5077, ISSN 0003-2700
Wydawca: American Chemical Society
DOI: 10.1021/acs.analchem.3c03007

Polysilicate Porous Organic Polymers (PSiPOPs), a Family of Porous, Ordered 3D Reticular Materials with Polysilicate Nodes and Organic Linkers

Autorzy: Jelle Jamoul; Sam Smet; Sambhu Radhakrishnan; C. Vinod Chandran; Johan A. Martens; Eric Breynaert
Opublikowane w: Chemistry of Materials, Numer Vol. 36; iss. 3, 2024, Strona(/y) 1385-1394, ISSN 0897-4756
Wydawca: American Chemical Society
DOI: 10.1021/acs.chemmater.3c02546

Reversible Parahydrogen Induced Hyperpolarization of 15N in Unmodified Amino Acids Unraveled at High Magnetic Field

Autorzy: Ewoud Vaneeckhaute; Jean-Max Tyburn; James G. Kempf; Johan A. Martens; Eric Breynaert
Opublikowane w: Advanced Science, Numer Vol. 10; iss. 23, 2023, ISSN 2198-3844
Wydawca: Wiley-VCH GmbH
DOI: 10.1002/advs.202207112

Enabling hydrate-based methane storage under mild operating conditions by periodic mesoporous organosilica nanotubes

Autorzy: Emile Jules Beckwée; Geert Watson; Maarten Houlleberghs; Daniel Arenas Esteban; Sara Bals; Pascal Van Der Voort; Eric Breynaert; Johan Martens; Gino V. Baron; Joeri F.M. Denayer
Opublikowane w: Heliyon, Numer Vol. 9; iss. 7, 2023, ISSN 2405-8440
Wydawca: Elsevier
DOI: 10.1016/j.heliyon.2023.e17662

HSIL-Based Synthesis of Ultracrystalline K,Na-JBW, a Zeolite Exhibiting Exceptional Framework Ordering and Flexibility

Autorzy: Karel Asselman; Sambhu Radhakrishnan; Nick Pellens; C. Vinod Chandran; Maarten Houlleberghs; Yijue Xu; Johan A. Martens; Sreeprasanth Pulinthanathu Sree; Christine E.A. Kirschhock; Eric Breynaert
Opublikowane w: Chemistry of Materials, Numer 08974756, 2022, Strona(/y) 7159–7166, ISSN 0897-4756
Wydawca: American Chemical Society
DOI: 10.1021/acs.chemmater.2c01059

Hydrogen bonding to oxygen in siloxane bonds drives liquid phase adsorption of primary alcohols in high-silica zeolites

Autorzy: Sambhu Radhakrishnan; Charlotte Lejaegere; Karel Duerinckx; Wei-Shang Lo; Alysson F. Morais; Dirk Dom; C. Vinod Chandran; Ive Hermans; Johan A. Martens; Eric Breynaert
Opublikowane w: Materials Horizons, Numer Vol. 10, 2023, Strona(/y) 3702-3711, ISSN 2051-6347
Wydawca: Royal Society of Chemistry
DOI: 10.1039/d3mh00888f

Strongly Reducing (Diarylamino)benzene-Based Covalent Organic Framework for Metal-Free Visible Light Photocatalytic H2O2 Generation

Autorzy: Chidharth Krishnaraj, Himanshu Sekhar Jena, Laurens Bourda, Andreas Laemont, Pradip Pachfule, Jerome Roeser, Vinod C Chandran, Sander Borgmans, Sven MJ Rogge, Karen Leus, Christian Stevens, Johan A Martens, Veronique Van Speybroeck, Eric Breynaert, Arne Thomas, Pascal Van der Voort
Opublikowane w: Journal Of The American Chemical Society, Numer Vol. 142; iss. 47, 2020, Strona(/y) 20107 - 20116, ISSN 0002-7863
Wydawca: American Chemical Society
DOI: 10.1021/jacs.0c09684

Online Solid-Phase Extraction–Gas Chromatography–Flame Ionization Detection System for Monitoring Contaminants at Parts-Per-Trillion Concentrations in Process Waters

Autorzy: Lejaegere, Charlotte; Vercammen, Joeri; Verheyden, Loes; Martens, Johan
Opublikowane w: Lc Gc Europe, Numer Vol. 36; iss. 01, 2023, Strona(/y) 7-13, ISSN 1471-6577
Wydawca: Advanstar Communications Inc.
DOI: 10.56530/lcgc.eu.eb6169h7

IZM-7: A new stable aluminosilicogermanate with a promising catalytic activity

Autorzy: El Hayek, E.; Radhakrishnan, S.; Vanbutsele, G.; Pulinthanathu Sree, S.; Rivallan, M.; Soyer, E.; Bouchy, C.; Breynaert, Eric; Martens, J.; Chizallet, C.; Harbuzaru, B.
Opublikowane w: Journal of Catalysis, Numer 00219517, 2021, Strona(/y) 601-605, ISSN 0021-9517
Wydawca: Academic Press
DOI: 10.1016/j.jcat.2021.11.006

NMR crystallography reveals carbonate induced Al-ordering in ZnAl layered double hydroxide

Autorzy: Sambhu Radhakrishnan; Karl Lauwers; C. Vinod Chandran; Julien Trébosc; Sreeprasanth Pulinthanathu Sree; Johan A. Martens; Francis Taulelle; Christine E. A. Kirschhock; Eric Breynaert
Opublikowane w: Chemistry—A European Journal, Numer 3, 2021, ISSN 0947-6539
Wydawca: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202101275

Engineering of hollow periodic mesoporous organosilica nanorods for augmented hydrogen clathrate formation

Autorzy: Geert Watson; Nithin B. Kummamuru; Sammy W. Verbruggen; Patrice Perreault; Maarten Houlleberghs; Johan Martens; Eric Breynaert; Pascal Van Der Voort
Opublikowane w: Journal of Materials Chemistry A, Numer Vol. 11, 2023, Strona(/y) 26265-26276, ISSN 2050-7488
Wydawca: Royal Society of Chemistry
DOI: 10.1039/d3ta05530b

How Water and Ion Mobility Affect the NMR Fingerprints of the Hydrated JBW Zeolite: a Combined Computational-Experimental Investigation

Autorzy: Vanlommel, S.; Hoffman, A. E. J.; Smet, S.; Radhakrishnan, S.; Asselman, K.; Chandran, C. V.; Breynaert, E.; Kirschhock, C. E. A.; Martens, J. A.; Van Speybroeck, V.
Opublikowane w: Chemistry-A European Journal, Numer 09476539, 2022, ISSN 0947-6539
Wydawca: John Wiley & Sons Ltd.
DOI: 10.1002/chem.202202621

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