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Zawartość zarchiwizowana w dniu 2024-05-07

Low oxidation state metal complexes and their role in organic synthesis

Cel



Organic compounds of metals (M) are of seminal importance, as reagents catalysts. The current most extensively studied are those in which M is one of the 14 lanthanides. Leaders include powerful USA and Japanese groups; in the EU, Lappert's group is prominent.
Despite serious efforts, oxidation states other than +3 for such compounds are restricted to +2 for Sm, Eu and Yb, and +4 for three Ce compounds; the former are valuable reducing agents (c.f. a recent Japanese monograph and an American review).
The project will make a timely contribution to one of the most competitive areas of organometallic chemistry. There are two major themes: (i) synthesis and structures of organic compounds of lanthanides in +1, +2 and +4 oxidation states, and (ii) their role as reagents and catalysts in organic chemical transformations. The results may have industrial significance as well as being of fundamental scientific importance.

Dziedzina nauki (EuroSciVoc)

Program(-y)

Temat(-y)

Zaproszenie do składania wniosków

Brak dostępnych danych

System finansowania

RGI - Research grants (individual fellowships)

Koordynator

University of Sussex
Wkład UE
Brak danych
Adres
Falmer
BN1 9QJ Brighton
Zjednoczone Królestwo
Koszt całkowity
Brak danych

Uczestnicy (1)