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Zawartość zarchiwizowana w dniu 2024-05-07

Palladium catalysed molecular switching cascades

Cel



Metal catalysts can provide a very effective approach to controlled "co-polymeri- sation" of 2,34....n different small molecular building blocks. Such reactions are cascade reactions and this approach offers the ultimate technology especially if the complex molecules required by the agrochemical and pharmaceutical industries, can largely be prepared from a series of small "off-the-shelf" building blocks. What is needed is a good understanding of the relative rates of potentially competing processed and the development of protocols for selectively promoting/suppressing some of these. This will provide the tools necessary to develop controlled cascades involving combinations of 2,34....n different substrate molecules which switch between intra- and inter-molecular cascade processes. Such processes offer immense power and startling increases in molecular complexity far outstripping conventional synthesis. The cascades comprise 3 widely variable components starter, switch and capping agent and a range of initiation methods and chiral catalysts will be developed.

Dziedzina nauki (EuroSciVoc)

Program(-y)

Temat(-y)

Zaproszenie do składania wniosków

Brak dostępnych danych

System finansowania

RGI - Research grants (individual fellowships)

Koordynator

UNIVERSITY OF LEEDS
Wkład UE
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Adres
Woodhouse Lane
LS2 9JT LEEDS
Zjednoczone Królestwo
Koszt całkowity
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Uczestnicy (1)